FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3086010168> ?p ?o ?g. }

• W3086010168 endingPage "15" @default.
• W3086010168 startingPage "3" @default.
• W3086010168 abstract "ConspectusA new generation of semiconducting materials based on metal halide perovskites has recently been launched into the scientific spotlight, exhibiting outstanding optoelectronic properties and providing promise for the development of efficient optical devices. As a vivid example, solar cells made from these materials have quickly reached conversion efficiencies exceeding 25%, now on par with well-established technologies, like silicon. Their widespread success is due, in part, to a unique ability to retain high-quality optoelectronic performance while being easily solution-processed into thin films. This feature is what defines them as a brand-new class of optoelectronic materials, with the ability to compete with traditional semiconductors requiring higher processing costs, like the III–Vs or II–IVs. However, the interesting photophysics of metal halide perovskites come with a catch; their soft ionic lattice promotes complex thermal-induced phase transitions and a high capacity for postsynthetic compositional changes, e.g., halide anion exchange. Such dynamic behavior has ultimately made understanding several important structure–property relationships ambiguous and obstructed a clear path toward commercialization due to inherent phase instability.Our aim in this Account is to highlight the fundamental aspects of metal halide perovskites that dictate a stable crystal structure and enable efficient anion exchange, through the lens of thermodynamic preference and phase formation energies. Taking the all-inorganic CsPbI3-xBrx system as a suitable case study, we focus on several ways in which its thermodynamically unstable perovskite structure can be maintained at room temperature and elucidate the restructuring pathways taken during destabilization. In addition, we will discuss the origin and mechanisms of postsynthetic anion exchange in CsPbX3 (X = I, Br, Cl) perovskites, with emphasis made toward direct visualization using in situ optical microspectroscopy and arriving at quantitative results. For several notable features of halide perovskites dealt with in this Account, e.g., strain stabilization, nonperovskite phase restructuring pathway, and lattice anion diffusion, we attempt to rationalize them using state-of-the-art materials modeling techniques.It is within this spirit that we not only modify a broad range of properties existing within metal halide perovskites but also regulate them for enhanced material functionality. For example, controlling partial phase changes and local replacement of halide composition in CsBX3 (B = Pb, Sn and X = I, Br, Cl) nanowires can facilitate the formation of optoelectronic heterojunctions, due to the abrupt change in local crystal structure and the correlated transition in optoelectronic properties. From this combined perspective, metal halide perovskites appear as highly dynamic systems, whereby structural and compositional modifications have a large impact on the underlying phase stability and optoelectronic properties. Thus, we highlight several scientific aspects important to the fundamental understanding of metal halide perovskites, ranging from the underlying mechanism and kinetics through which phase destabilization and anion exchange take place, to tuning the thermodynamic energy landscape using external stimuli. We anticipate that providing a clear perspective for these topics will help deepen our knowledge of the nature of ionic semiconductors and provide the stimulus required to build new research directions toward utilizing halide perovskites within versatile optoelectronic devices." @default.
• W3086010168 created "2020-09-21" @default.
• W3086010168 creator A5010426030 @default.
• W3086010168 creator A5018679971 @default.
• W3086010168 creator A5030085518 @default.
• W3086010168 creator A5051766563 @default.
• W3086010168 creator A5057303247 @default.
• W3086010168 creator A5070216663 @default.
• W3086010168 creator A5078485962 @default.
• W3086010168 date "2020-09-14" @default.
• W3086010168 modified "2023-10-18" @default.
• W3086010168 title "Phase Transitions and Anion Exchange in All-Inorganic Halide Perovskites" @default.
• W3086010168 cites W1578113917 @default.
• W3086010168 cites W1849148947 @default.
• W3086010168 cites W1946383872 @default.
• W3086010168 cites W1963721320 @default.
• W3086010168 cites W1965464747 @default.
• W3086010168 cites W1977057564 @default.
• W3086010168 cites W1991981401 @default.
• W3086010168 cites W1999717631 @default.
• W3086010168 cites W2008207699 @default.
• W3086010168 cites W2008676742 @default.
• W3086010168 cites W2019162166 @default.
• W3086010168 cites W2026226021 @default.
• W3086010168 cites W2039864133 @default.
• W3086010168 cites W2040157298 @default.
• W3086010168 cites W2041391801 @default.
• W3086010168 cites W2041726686 @default.
• W3086010168 cites W2042468043 @default.
• W3086010168 cites W2050079556 @default.
• W3086010168 cites W2050873565 @default.
• W3086010168 cites W2057327293 @default.
• W3086010168 cites W2089224041 @default.
• W3086010168 cites W2125469086 @default.
• W3086010168 cites W2139755213 @default.
• W3086010168 cites W2155176366 @default.
• W3086010168 cites W2167590372 @default.
• W3086010168 cites W2169328609 @default.
• W3086010168 cites W2177482128 @default.
• W3086010168 cites W2182558273 @default.
• W3086010168 cites W2190353957 @default.
• W3086010168 cites W2265691491 @default.
• W3086010168 cites W2403013067 @default.
• W3086010168 cites W2407518462 @default.
• W3086010168 cites W2415832373 @default.
• W3086010168 cites W2464416233 @default.
• W3086010168 cites W2507772826 @default.
• W3086010168 cites W2509065353 @default.
• W3086010168 cites W2527042386 @default.
• W3086010168 cites W2537132801 @default.
• W3086010168 cites W2549727999 @default.
• W3086010168 cites W2554532276 @default.
• W3086010168 cites W2563173531 @default.
• W3086010168 cites W2591842075 @default.
• W3086010168 cites W2593574896 @default.
• W3086010168 cites W2607200708 @default.
• W3086010168 cites W2622706513 @default.
• W3086010168 cites W2711335539 @default.
• W3086010168 cites W2740374132 @default.
• W3086010168 cites W2767027396 @default.
• W3086010168 cites W2767767460 @default.
• W3086010168 cites W2770830442 @default.
• W3086010168 cites W2773857860 @default.
• W3086010168 cites W2780504473 @default.
• W3086010168 cites W2785018848 @default.
• W3086010168 cites W2785060548 @default.
• W3086010168 cites W2789714093 @default.
• W3086010168 cites W2791515348 @default.
• W3086010168 cites W2803594777 @default.
• W3086010168 cites W2886231050 @default.
• W3086010168 cites W2887803723 @default.
• W3086010168 cites W2888039751 @default.
• W3086010168 cites W2889493318 @default.
• W3086010168 cites W2899786547 @default.
• W3086010168 cites W2912440600 @default.
• W3086010168 cites W2942588561 @default.
• W3086010168 cites W2946148141 @default.
• W3086010168 cites W2952161223 @default.
• W3086010168 cites W2962719951 @default.
• W3086010168 cites W2965937470 @default.
• W3086010168 cites W2988400808 @default.
• W3086010168 cites W2995198679 @default.
• W3086010168 cites W3001744677 @default.
• W3086010168 cites W3006652110 @default.
• W3086010168 cites W3020956046 @default.
• W3086010168 cites W3022100902 @default.
• W3086010168 cites W3022635738 @default.
• W3086010168 cites W3046975173 @default.
• W3086010168 cites W4205310234 @default.
• W3086010168 cites W626665579 @default.
• W3086010168 doi "https://doi.org/10.1021/accountsmr.0c00009" @default.
• W3086010168 hasPublicationYear "2020" @default.
• W3086010168 type Work @default.
• W3086010168 sameAs 3086010168 @default.
• W3086010168 citedByCount "57" @default.
• W3086010168 countsByYear W30860101682020 @default.
• W3086010168 countsByYear W30860101682021 @default.
• W3086010168 countsByYear W30860101682022 @default.

• next