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- W3086036923 endingPage "6864" @default.
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- W3086036923 abstract "Here, we report our findings related to the structural and electronic considerations that influence the rate of oxygen-atom transfer (OAT) to oxygen-deficient polyoxovanadate alkoxide (POV-alkoxide) clusters ([V6O6(OC2H5)12]n; n = 1–, 0, 1+). A comparison of the reaction times required for the reduction of nitrogen-containing oxyanions (NOx–, x = 2, 3) by the POV-ethoxide cluster in its anionic (1-V6O61–; VIIIVIV5), neutral (4-V6O60; VIIIVIV4VV), or cationic (6-V6O61+; VIIIVIV3VV2) charge state reveals that OAT is significantly influenced by three factors: (1) ion-pairing interactions between the POV-alkoxide and the negatively charged oxyanion; (2) oxidation states of remote vanadyl ions in the Lindqvist assembly; (3) the steric bulk surrounding the coordinatively unsaturated VIII ion. This work provides atomic-level insight related to structure–function relationships that govern the rate of OAT at metal oxide surfaces using polyoxometalate clusters as molecular models." @default.
- W3086036923 created "2020-09-21" @default.
- W3086036923 creator A5016331643 @default.
- W3086036923 creator A5048869876 @default.
- W3086036923 date "2020-09-14" @default.
- W3086036923 modified "2023-10-03" @default.
- W3086036923 title "Physicochemical Factors That Influence the Deoxygenation of Oxyanions in Atomically Precise, Oxygen-Deficient Vanadium Oxide Assemblies" @default.
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- W3086036923 doi "https://doi.org/10.1021/acs.inorgchem.0c02052" @default.
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