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• W3086881504 startingPage "123968" @default.
• W3086881504 abstract "Though commonly used in the dewatering of textile dyeing sludge (TDS) before its incineration, chemical conditioning has yet to be evaluated in terms of its impact on the reaction mechanisms, emissions, and ash minerals. This study combined experiments and equilibrium simulations to disentangle the interaction mechanism among the combustion behaviors, gas emissions, ash minerals of TDS conditioned with(out) three blend ratios of the AlCl 3 conditioner. The use of the AlCl 3 conditioner slightly improved the performance of the combustion stage of volatiles and chars. No significant effect of AlCl 3 conditioner was detected on the kinetic mechanism of its main combustion stage best elucidated by the n th-order and diffusion models. SO 2 was the main evolved gas whose reduction between 600 and 800 °C was attributed to its increased retention rate by CaO from the decomposition of CaCO 3 . Aluminum compounds acted as a stimulator in SO 2 emission between 800 and 1000 °C since the formation of calcium aluminosilicates. At above 1060 °C, CaSO 4 decomposed rapidly, thus almost completely releasing inorganic S. This study supplies new insights into pollution `controls on the combustion of TDS conditioned with Al salt coagulant. • The use of AlCl 3 improved the combustion performance of textile dyeing sludge. • Reaction mechanism changed from a n th-order model to a diffusion model. • SO 2 was the main gaseous pollutant. • Insights into emission control were provided combining experiments and simulations. • The formation of calcium aluminosilicates enhanced SO 2 emission." @default.
• W3086881504 created "2020-09-21" @default.
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• W3086881504 date "2021-02-01" @default.
• W3086881504 modified "2023-10-09" @default.
• W3086881504 title "Coupled mechanisms of reaction kinetics, gas emissions, and ash mineral transformations during combustion of AlCl3-conditioned textile dyeing sludge" @default.
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• W3086881504 doi "https://doi.org/10.1016/j.jhazmat.2020.123968" @default.
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