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- W3087017006 abstract "Using a minimal algebraic model for the thermodynamics of binary rod--polymer mixtures, we provide evidence for a quintuple phase equilibrium; an observation that seems to be at odds with the Gibbs phase rule for two-component systems. Our model is based on equations of state for the relevant liquid crystal phases that are in quantitative agreement with computer simulations. We argue that the appearance of a quintuple equilibrium, involving an isotropic fluid, a nematic and smectic liquid crystal, and two solid phases can be reconciled with a generalized Gibbs phase rule in which the two intrinsic length scales of the athermal colloid--polymer mixture act as additional field variables." @default.
- W3087017006 created "2020-09-25" @default.
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- W3087017006 date "2020-09-18" @default.
- W3087017006 modified "2023-10-11" @default.
- W3087017006 title "Defying the Gibbs Phase Rule: Evidence for an Entropy-Driven Quintuple Point in Colloid-Polymer Mixtures" @default.
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- W3087017006 doi "https://doi.org/10.1103/physrevlett.125.127803" @default.
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