FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3087299502> ?p ?o ?g. }

• W3087299502 endingPage "129292" @default.
• W3087299502 startingPage "129292" @default.
• W3087299502 abstract "• A good quality organic crystal piperazine-1,4-diium bis(2,4-dichlorobenzoate) (PBDCB) was grown. • PBDCB single crystal was discovered to be monoclinic system with centrosymmetric space group P2 1 /c by single crystal X-ray analysis and found optical band gap energy (3.9 eV). • TGA/DTA thermal studies reveal that PBDCB was thermally stable up to 163 °C. • Laser damage threshold value of PBDCB was obtained to be 8.97 GW/cm 2 . • Z -scan analysis exhibit PBDCB is a promising material for NLO application. A novel third-nonlinear optical (NLO) crystal, piperazine-1,4-diium bis(2,4-dichlorobenzoate) (abbreviated as PBDCB) was successfully synthesized and grown good quality crystal by slow evaporation solution growth technique by methanol as a solvent at room temperature. The formation of the grown crystal was carried out by single-crystal X-ray diffraction analysis. The analysis of a single crystal X-ray diffraction reveals that the title compound was crystallized in the monoclinic system with centrosymmetric space group P2 1 /c and thereof lattice parameter are a = 11.166(6) Å, b = 8.160(5) Å, c = 12.085(6) Å, β= 113.18(3)°, Z = 4. Crystallographic studies also reveal that the molecules are linked via N—H···O and C—H···Cl hydrogen bonds. Pairs of intermolecular N—H···O hydrogen bonds generate R 4 4 (12) ring motifs. The powder X-ray diffraction study was completed and the peaks were indexed. UV–Vis spectral studies were revealed that the grown crystal is transparent in the entire visible region with a lower cut off the wavelength of 286 nm. The optical band gap of the title compound was measured by Tauc's plot method, and it was obtained to be 3.9 eV, which shows suitable applications of the optoelectronic device. In the photoluminescence study, the grown crystal was revealed violet emission radiation, and thereof peak has appeared at 312 nm. The functional groups of the grown crystal have been determined by Fourier Transform Infra-Red (FTIR) spectroscopy technique. In thermogravimetric (TGA) and differential thermal analysis (DTA) analysis, the title material was determined as thermally as stable up to 163 °C. The Vickers Microhardness test ascertained the mechanical properties of the grown crystal material, and it belongs to a soft material category. The dielectric measurements of the developed crystal material were also ascertained at various frequencies. The dielectric constant, dielectric loss, and A.C. the conductivity of title material was studied with different frequencies and temperatures. The laser damage threshold (LDT) of the grown crystal was then calculated by using Nd: YAG laser. The grown crystal has given the measured (LDT) value of 8.97 GW/cm 2 . The third-order nonlinear optical (NLO) properties characteristics, such as absorption coefficient (β ~ 0.02 × 10 −4 cm/W), the refractive index (n 2 ~ 4.06 × 10 −8 cm 2 /W), and their susceptibility range values of (χ (3) ~ 2.17 × 10 −6 esu) of the grown crystal was estimated by Z-scan technique, suggests that the grown crystal material PBDCB was served as a promising source for nonlinear optical devices." @default.
• W3087299502 created "2020-09-25" @default.
• W3087299502 creator A5002353789 @default.
• W3087299502 creator A5008700319 @default.
• W3087299502 creator A5068282811 @default.
• W3087299502 creator A5076806279 @default.
• W3087299502 creator A5078568056 @default.
• W3087299502 creator A5081986834 @default.
• W3087299502 creator A5084269364 @default.
• W3087299502 date "2021-02-01" @default.
• W3087299502 modified "2023-10-16" @default.
• W3087299502 title "Growth, structural, spectral, optical and thermal studies of a novel third-order nonlinear optical single crystal: Piperazine-1,4-diium bis(2, 4-dichlorobenzoate)" @default.
• W3087299502 cites W1969360633 @default.
• W3087299502 cites W1971647216 @default.
• W3087299502 cites W1971668186 @default.
• W3087299502 cites W1972850178 @default.
• W3087299502 cites W1973921447 @default.
• W3087299502 cites W1981654362 @default.
• W3087299502 cites W1982414593 @default.
• W3087299502 cites W1986510939 @default.
• W3087299502 cites W1989650526 @default.
• W3087299502 cites W1991974428 @default.
• W3087299502 cites W1994404792 @default.
• W3087299502 cites W1997038012 @default.
• W3087299502 cites W1997380582 @default.
• W3087299502 cites W2002417837 @default.
• W3087299502 cites W2004054529 @default.
• W3087299502 cites W2010000345 @default.
• W3087299502 cites W2010681440 @default.
• W3087299502 cites W2011207907 @default.
• W3087299502 cites W2013538542 @default.
• W3087299502 cites W2019429537 @default.
• W3087299502 cites W2019882965 @default.
• W3087299502 cites W2023080281 @default.
• W3087299502 cites W2026711370 @default.
• W3087299502 cites W2031836568 @default.
• W3087299502 cites W2032323093 @default.
• W3087299502 cites W2034320149 @default.
• W3087299502 cites W2035233311 @default.
• W3087299502 cites W2038975489 @default.
• W3087299502 cites W2043750460 @default.
• W3087299502 cites W2047405766 @default.
• W3087299502 cites W2051052363 @default.
• W3087299502 cites W2052470530 @default.
• W3087299502 cites W2057410487 @default.
• W3087299502 cites W2057420484 @default.
• W3087299502 cites W2065204718 @default.
• W3087299502 cites W2065249727 @default.
• W3087299502 cites W2068482195 @default.
• W3087299502 cites W2074770928 @default.
• W3087299502 cites W2077960384 @default.
• W3087299502 cites W2080965426 @default.
• W3087299502 cites W2081238346 @default.
• W3087299502 cites W2082303816 @default.
• W3087299502 cites W2091441807 @default.
• W3087299502 cites W2093555433 @default.
• W3087299502 cites W2094498700 @default.
• W3087299502 cites W2097578667 @default.
• W3087299502 cites W2098780834 @default.
• W3087299502 cites W2125097568 @default.
• W3087299502 cites W2132454074 @default.
• W3087299502 cites W2141324595 @default.
• W3087299502 cites W2147304506 @default.
• W3087299502 cites W2166217280 @default.
• W3087299502 cites W2177780143 @default.
• W3087299502 cites W2272373809 @default.
• W3087299502 cites W2274469715 @default.
• W3087299502 cites W2322386508 @default.
• W3087299502 cites W2345339691 @default.
• W3087299502 cites W2417398819 @default.
• W3087299502 cites W2520696903 @default.
• W3087299502 cites W2624797412 @default.
• W3087299502 cites W2738015656 @default.
• W3087299502 cites W2770041802 @default.
• W3087299502 cites W2787833544 @default.
• W3087299502 cites W2791117328 @default.
• W3087299502 cites W2793146636 @default.
• W3087299502 cites W2806906694 @default.
• W3087299502 cites W2809465120 @default.
• W3087299502 cites W2894246545 @default.
• W3087299502 cites W2900347068 @default.
• W3087299502 cites W2903598718 @default.
• W3087299502 cites W2905813745 @default.
• W3087299502 cites W2916739871 @default.
• W3087299502 cites W2921831621 @default.
• W3087299502 cites W2944306014 @default.
• W3087299502 cites W2963758828 @default.
• W3087299502 cites W2967683461 @default.
• W3087299502 cites W2971934481 @default.
• W3087299502 cites W2972281408 @default.
• W3087299502 cites W2977597722 @default.
• W3087299502 cites W2984564496 @default.
• W3087299502 cites W2999295243 @default.
• W3087299502 cites W2999978930 @default.
• W3087299502 cites W3002300056 @default.
• W3087299502 cites W3002865891 @default.
• W3087299502 cites W3029774515 @default.
• W3087299502 cites W3030842874 @default.

• next