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- W3087742412 startingPage "119549" @default.
- W3087742412 abstract "The oxo-Co/phosphate based material (CoPi) developed by Kanan and Nocera in 2008 is among the most outstanding catalysts for water oxidation at neutral pH. The remarkable performance and striking properties of CoPi reside on its intriguing and unique structure. In the present contribution, TEM, SAED, UV-vis-NIR absorption and Raman spectroscopy were performed at 77 K, complemented by room temperature experiments, to unprecedentedly reveal that CoPi is composed by short-range ordered β-NaCoPO4 (a solid ionic conductor) and expanded-lattice Co3O4 clusters with electronic structures, vibrational responses and catalytic properties quite deviated from those of their bulk counterparts. Internal morphological features of CoPi are also disclosed. Consequently, some aspects of the previously proposed structure and operating mechanisms are revised. This study derived in a deposition route which yields CoPi layers that outperforms, as water oxidation catalyst, the traditionally electrodeposited CoPi." @default.
- W3087742412 created "2020-09-25" @default.
- W3087742412 creator A5015319404 @default.
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- W3087742412 date "2021-03-01" @default.
- W3087742412 modified "2023-10-17" @default.
- W3087742412 title "Unraveling amazing structural features of a highly efficient “oxo-Co/phosphate” catalyst for water oxidation" @default.
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- W3087742412 doi "https://doi.org/10.1016/j.apcatb.2020.119549" @default.
- W3087742412 hasPublicationYear "2021" @default.
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