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• W3087849950 endingPage "1914" @default.
• W3087849950 startingPage "1908" @default.
• W3087849950 abstract "Bacterial cellulose (BC), prepared from two recently developed thermotolerant bacterial strains (Komagataeibacter xylinus C30 and Komagataeibacter oboediens R37–9), were used as a raw material to synthesize nanofibril films. Field-emission scanning electron microscope (FE-SEM) observations confirmed the ultrafine nano-structure of BC pellicle (BCP) with average fibril widths between 50 and 60 nm. The BC was directly oxidized in a TEMPO/NaBr/NaClO system at pH of 10 for 2 h. TEMPO-oxidized bacterial cellulose nanofibrils (TOBCN) were obtained by a mild mechanical treatment and the TOBCN films were prepared through heat-drying. The oxidation yielded a recovery ratio between 70 and 80% by weight with an increase in the carboxylate content of 0.9–1.0 mmol g −1. Nanofibrillation yields were more than 90% and the resulting high aspect ratio TOBCNs were ~6 nm in average width with >800 nm in lengths, when observed under transmission electron microscope (TEM). TOBCN film of K. xylinus C30 exhibited high transparency (79%), tensile strength (142 MPa), Young's modulus (7.13 GPa), elongation around failure (3.89%), and work of fracture (2.29 MJ m−3), when compared to the TOBCN films of K. oboediens R37–9 at 23 °C and 50% RH. Coefficients of thermal expansion of both the TOBCN films were low at around 6 ppm K−1." @default.
• W3087849950 created "2020-10-01" @default.
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• W3087849950 date "2020-11-01" @default.
• W3087849950 modified "2023-10-16" @default.
• W3087849950 title "TEMPO-oxidized cellulose nanofibril film from nano-structured bacterial cellulose derived from the recently developed thermotolerant Komagataeibacter xylinus C30 and Komagataeibacter oboediens R37–9 strains" @default.
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• W3087849950 doi "https://doi.org/10.1016/j.ijbiomac.2020.09.124" @default.
• W3087849950 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32976905" @default.
• W3087849950 hasPublicationYear "2020" @default.
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