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- W3088077897 abstract "SnS with high theoretical capacity is a promising anode material for lithium-ion batteries. However, dramatic volume changes of SnS during repeated discharge/charge cycles result in fractures or even pulverization of electrode, leading to rapid capacity degradation. To solve this problem, we construct a dual-carbon-confined SnS nanostructure (denoted as SnS@C/rGO) by depositing semi-graphitized carbon layers on reduced graphene oxide (rGO) supported SnS nanoplates during high-temperature reduction. The dual carbon of rGO and in situ formed carbon coating confines growth of SnS during the high-temperature calcination. Moreover, during the reversible Li+ storage the dual-carbon modification enables good electronic conductivity, relieves the volume effect, and provides double insurance for the electrical contact of SnS even after repeated cycles. Benefiting from the dual-carbon confinement, SnS@C/rGO exhibits significantly enhanced rate capability and cycling stability compared with the bare and single carbon modified SnS. SnS@C/rGO presents reversible capacity of 1029.8 mAh g−1 at 0.2 A g−1. Even at a high current density of 1 A g−1, it initially delivers reversible capacity of 934.0 mAh g−1 and retains 98.2% of the capacity (918.0 mAh g−1) after 330 cycles. This work demonstrates potential application of dual-carbon modification in the development of electrode materials for high-performance lithium-ion batteries." @default.
- W3088077897 created "2020-10-01" @default.
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- W3088077897 date "2020-10-29" @default.
- W3088077897 modified "2023-10-15" @default.
- W3088077897 title "Dual‐Carbon‐Confined SnS Nanostructure with High Capacity and Long Cycle Life for Lithium‐ion Batteries" @default.
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- W3088077897 doi "https://doi.org/10.1002/eem2.12136" @default.
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