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- W3088214519 abstract "Ligand exchange reactions between a Hoveyda–Grubbs-type complex and 2-alkoxybenzylidene in a biomolecule assist in the delivery of a ruthenium complex unit to the biomolecule. Complexes having an electron-withdrawing group in their ligands efficiently transfer a ruthenium complex unit onto peptides. This method is also applicable for adenylate kinase, an experimental model protein. The ligand exchange reaction originates from ruthenium-olefin specific interactions and potentially provides a bioorthogonal method for chemical modification of biomacromolecules with transition metal complexes. Ligand exchange between a Hoveyda-Grubbs-type complex and a 2-alkoxybenzylidene moiety on a peptide or a protein is a useful reaction to immobilize a ruthenium complex unit onto biomolecules under polar conditions. This method is based on a ruthenium–olefin specific interaction and will be applicable as a bioorthogonal chemical modification strategy for biomacromolecules with transition metal complexes." @default.
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- W3088214519 date "2020-12-05" @default.
- W3088214519 modified "2023-10-16" @default.
- W3088214519 title "Ligand Exchange Strategy for Delivery of Ruthenium Complex Unit to Biomolecules Based on Ruthenium–Olefin Specific Interactions" @default.
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- W3088214519 doi "https://doi.org/10.1246/cl.200590" @default.
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