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- W3088392715 abstract "Abstract The oxidation of pure docosahexaenoic acid (DHA, C22:6 ω3), eicosapentaenoic acid (EPA, C20:5 ω3), conjugated linoleic acid (CLA, C18:2), and trans ‐vaccenic acid (TVA, C18:1 t11) was assessed using differential scanning calorimetry (DSC) at six heating rates (3–18 K min −1 ) within a range of 300–600 K. The DSC spectra were analyzed using iso‐conversional kinetics to calculate the pre‐exponential factor ( A o ), activation energy ( E o ), and reaction model ( f ( α ) ). The E o for DHA, EPA, CLA, and TVA varied from 33–40, 36–49, 48–64, and 64–92 kJ/mol, respectively. The A o were 2.87 ± 0.03, 4.42 ± 0.21, 24.94 ± 1.31, and 580.91 ± 4.61 min −1 for DHA, EPA, CLA, and TVA, respectively. The comparison of the numerically reconstructed model with theoretical values showed that the oxidation of DHA and EPA was best described by an Avrami‐Erofeev model, while a three‐dimensional diffusion model best described the oxidation of CLA and TVA. Practical applications The application of iso‐conversional kinetics to study the oxidation of bioactive milk lipids provides a mathematical tool for describing the oxidation regardless of the complexity of the process. The oxidation of bioactive milk lipids can be modeled using the obtained values of the kinetic triplet. Such modeling can be performed without knowing the mechanisms, which typically involves the use of sophisticated analytical techniques. The obtained results may enable further process development, design, and optimization." @default.
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- W3088392715 date "2020-09-15" @default.
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- W3088392715 title "Kinetic analysis of non‐isothermal oxidation of bioactive milk lipids" @default.
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- W3088392715 doi "https://doi.org/10.1111/jfpe.13519" @default.
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