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- W3088432823 abstract "Abstract The natural starch (NS) is modified by an esterification process which is accomplished by reacting the NS and phosphate together with urea via a facile alcohol solvothermal method. After modification, a series of obvious variations can be easily confirmed for the resulted starch phosphate carbamides (denoted as SPC) compared with that of NS, such as the introduction of new groups of C O, P O, P-O-C and P-O-H together with new elements of N and P in starch molecular structure unit confirmed in FT-IR and XPS analyses and the decreased crystallinity along with formed surface defect demonstrated in XRD and SEM measurements. Furthermore, the formed SPC has a higher viscosity of 480 mPa.s−1 and lower gelatinization temperature of under 10 °C than that of the NS. More importantly, when the SPC is utilized as outer coating material together with ethylcellulose (EC) as inner coating material for preparing double-layer slow-release urea (denoted as EC/SPC based SRU), the EC/SPC based SRU has a desirable slow-release behavior with release percentages of 40.9% for 12 h in water and merely 59.6% for 20 day together with even exceeding 30 days in soil. Conclusively, this work provides a facile preparation approach for the SPC and its creative application for the preparation of SRU." @default.
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- W3088432823 date "2020-11-01" @default.
- W3088432823 modified "2023-10-18" @default.
- W3088432823 title "Esterification modified starch by phosphates and urea via alcohol solvothermal route for its potential utilization for urea slow-releasing" @default.
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- W3088432823 doi "https://doi.org/10.1016/j.ijbiomac.2020.09.186" @default.
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