FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3088648422> ?p ?o ?g. }

• W3088648422 endingPage "258" @default.
• W3088648422 startingPage "258" @default.
• W3088648422 abstract "Solar hydrogen production via the photoelectrochemical water-splitting reaction is attractive as one of the environmental-friendly approaches for producing H2. Since the reaction simultaneously generates H2 and O2, this method requires immediate H2 recovery from the syngas including O2 under high-humidity conditions around 50 °C. In this study, a supported mesoporous γ-Al2O3 membrane was modified with allyl-hydrido-polycarbosilane as a preceramic polymer and subsequently heat-treated in Ar to deliver a ternary SiCH organic–inorganic hybrid/γ-Al2O3 composite membrane. Relations between the polymer/hybrid conversion temperature, hydrophobicity, and H2 affinity of the polymer-derived SiCH hybrids were studied to functionalize the composite membranes as H2-selective under saturated water vapor partial pressure at 50 °C. As a result, the composite membranes synthesized at temperatures as low as 300–500 °C showed a H2 permeance of 1.0–4.3 × 10−7 mol m−2 s−1 Pa−1 with a H2/N2 selectivity of 6.0–11.3 under a mixed H2-N2 (2:1) feed gas flow. Further modification by the 120 °C-melt impregnation of low molecular weight polycarbosilane successfully improved the H2-permselectivity of the 500 °C-synthesized composite membrane by maintaining the H2 permeance combined with improved H2/N2 selectivity as 3.5 × 10−7 mol m−2 s−1 Pa−1 with 36. These results revealed a great potential of the polymer-derived SiCH hybrids as novel hydrophobic membranes for purification of solar hydrogen." @default.
• W3088648422 created "2020-10-01" @default.
• W3088648422 creator A5016673440 @default.
• W3088648422 creator A5019538225 @default.
• W3088648422 creator A5022043890 @default.
• W3088648422 creator A5041285540 @default.
• W3088648422 creator A5050797851 @default.
• W3088648422 creator A5061590341 @default.
• W3088648422 creator A5069380486 @default.
• W3088648422 creator A5072233775 @default.
• W3088648422 creator A5073089455 @default.
• W3088648422 creator A5078648922 @default.
• W3088648422 date "2020-09-25" @default.
• W3088648422 modified "2023-09-30" @default.
• W3088648422 title "Hydrogen Selective SiCH Inorganic–Organic Hybrid/γ-Al2O3 Composite Membranes" @default.
• W3088648422 cites W114139752 @default.
• W3088648422 cites W1970533506 @default.
• W3088648422 cites W1979822041 @default.
• W3088648422 cites W1980704616 @default.
• W3088648422 cites W1983349408 @default.
• W3088648422 cites W1984257022 @default.
• W3088648422 cites W1985057995 @default.
• W3088648422 cites W1989918784 @default.
• W3088648422 cites W1992212848 @default.
• W3088648422 cites W2001792451 @default.
• W3088648422 cites W2003172285 @default.
• W3088648422 cites W2017547395 @default.
• W3088648422 cites W2024971523 @default.
• W3088648422 cites W2034485241 @default.
• W3088648422 cites W2035840684 @default.
• W3088648422 cites W2043217416 @default.
• W3088648422 cites W2043777546 @default.
• W3088648422 cites W2047960425 @default.
• W3088648422 cites W2050074809 @default.
• W3088648422 cites W2050704564 @default.
• W3088648422 cites W2065943177 @default.
• W3088648422 cites W2068160413 @default.
• W3088648422 cites W2073326028 @default.
• W3088648422 cites W2078026041 @default.
• W3088648422 cites W2078888490 @default.
• W3088648422 cites W2080734168 @default.
• W3088648422 cites W2083364760 @default.
• W3088648422 cites W2089604358 @default.
• W3088648422 cites W209596556 @default.
• W3088648422 cites W2098693095 @default.
• W3088648422 cites W2103804115 @default.
• W3088648422 cites W2108029030 @default.
• W3088648422 cites W2130164470 @default.
• W3088648422 cites W2135580922 @default.
• W3088648422 cites W2137480479 @default.
• W3088648422 cites W2141975426 @default.
• W3088648422 cites W2158624388 @default.
• W3088648422 cites W2160792119 @default.
• W3088648422 cites W2225648033 @default.
• W3088648422 cites W2235679284 @default.
• W3088648422 cites W2297655526 @default.
• W3088648422 cites W2334338311 @default.
• W3088648422 cites W2343688887 @default.
• W3088648422 cites W2460097774 @default.
• W3088648422 cites W2599199563 @default.
• W3088648422 cites W2613229658 @default.
• W3088648422 cites W2753454358 @default.
• W3088648422 cites W2757061229 @default.
• W3088648422 cites W2775059840 @default.
• W3088648422 cites W2779265347 @default.
• W3088648422 cites W2782830115 @default.
• W3088648422 cites W2791677394 @default.
• W3088648422 cites W2791850854 @default.
• W3088648422 cites W2799303226 @default.
• W3088648422 cites W2886126294 @default.
• W3088648422 cites W2898699529 @default.
• W3088648422 cites W2903673395 @default.
• W3088648422 cites W2903972487 @default.
• W3088648422 cites W2969713893 @default.
• W3088648422 cites W2971349810 @default.
• W3088648422 cites W2973797246 @default.
• W3088648422 cites W2987268111 @default.
• W3088648422 cites W2997881867 @default.
• W3088648422 cites W3011861513 @default.
• W3088648422 cites W3014951782 @default.
• W3088648422 cites W3026382028 @default.
• W3088648422 cites W3028133846 @default.
• W3088648422 cites W3038060384 @default.
• W3088648422 cites W4240875974 @default.
• W3088648422 cites W4376849564 @default.
• W3088648422 doi "https://doi.org/10.3390/membranes10100258" @default.
• W3088648422 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7600925" @default.
• W3088648422 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32992911" @default.
• W3088648422 hasPublicationYear "2020" @default.
• W3088648422 type Work @default.
• W3088648422 sameAs 3088648422 @default.
• W3088648422 citedByCount "2" @default.
• W3088648422 countsByYear W30886484222022 @default.
• W3088648422 crossrefType "journal-article" @default.
• W3088648422 hasAuthorship W3088648422A5016673440 @default.
• W3088648422 hasAuthorship W3088648422A5019538225 @default.
• W3088648422 hasAuthorship W3088648422A5022043890 @default.
• W3088648422 hasAuthorship W3088648422A5041285540 @default.

• next