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- W3088828052 abstract "Herein, we describe an environmentally benign and cost‐effective protocol for the synthesis of valuable bifuranyl dicarboxylates, starting with α‐bromination of readily accessible furan‐2‐carboxylates by LiBr and K 2 S 2 O 8 . Furthermore, the bromination intermediate product 5‐bromofuran‐2‐carboxylates were then conducted in a palladium‐catalyzed reductive homocoupling reactions in the presence of alcohols to afford bifuranyl dicarboxylates. One of the final products in this protocol, [2,2’]bifuran‐5,5’‐dicarboxylic acid esters, are essential monomers of poly(ethylene bifuranoate), which can be served as an green and versatile alternative polymer for traditional poly(ethylene terephthalate) that is currently common in technical plastics." @default.
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- W3088828052 date "2020-12-07" @default.
- W3088828052 modified "2023-10-01" @default.
- W3088828052 title "Synthesis of [2,2’]Bifuranyl‐5,5’‐dicarboxylic Acid Esters <i>via</i> Reductive Homocoupling of <scp>5‐Bromofuran</scp> ‐2‐carboxylates Using Alcohols as Reductants <sup>†</sup>" @default.
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- W3088828052 doi "https://doi.org/10.1002/cjoc.202000303" @default.
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