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- W3089190504 abstract "A formal [3+2] cyclization mediated by silver(I) oxide and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) is described herein. Through a broad variety of carbonyl compounds, this system can promote cyclization reactions with high yield (up to 85 %) and diastereoselectivity (up to 95:5) for a straightforward access to complex and congested dihydrofuran derivatives in one step under mild conditions. Based on DFT studies, the proposed mechanism would involve an allenyl silver intermediate." @default.
- W3089190504 created "2020-10-01" @default.
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- W3089190504 date "2020-12-01" @default.
- W3089190504 modified "2023-10-18" @default.
- W3089190504 title "Silver(I) Oxide‐/DBU‐Promoted Synthesis of Dihydrofuran Units through Allenyl Silver Formation" @default.
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- W3089190504 doi "https://doi.org/10.1002/chem.202002696" @default.
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