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- W3089366185 abstract "An enantiomerically pure substance has paramount physiological importance. Synthetic chemists aimed to produce drug molecules primarily target to synthesize pure enantiomer. Enantiomers are optically active stereoisomers so in order to accomplish products with high enantiomeric excess, asymmetric synthesis must be designed judiciously. Mimicking nature’s selective aptitude of biosynthesis is always considered a crucial challenge for synthetic chemists. The main target of drug designing is to attain skill in this specialized section. Racemization during asymmetric synthesis occasionally disappoints synthetic chemists by widely disrupting biophysical, biochemical characteristics of the synthesized compound. Kinetic resolution, however, is able to separate two enantiomers. Among innumerable synthesis, only a few are found to be associated with high enantiomeric excess yield. Contribution of enantioselective epoxide synthesis by Sharpless epoxidation is no less important in drug industry. Most striking feature of Sharpless epoxidation is materials used for producing enantiospecific epoxide are inexpensive. Product spread consisting of one predominating chiral epoxide is efficiently resolved. The current communication is aimed to analyse Sharpless epoxidation from analytical angle of a chemist using a model study of transition state structure using DIPT as chiral auxiliary and drives to find the underlying basis responsible for channelizing only one enantiomer at the suppression of other." @default.
- W3089366185 created "2020-10-08" @default.
- W3089366185 creator A5034383958 @default.
- W3089366185 date "2020-09-30" @default.
- W3089366185 modified "2023-09-27" @default.
- W3089366185 title "Origin of Enantioselectivity: A Model Study of Sharpless Epoxidation" @default.
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- W3089366185 doi "https://doi.org/10.1007/978-981-15-7409-2_44" @default.
- W3089366185 hasPublicationYear "2020" @default.
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