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- W3089482015 abstract "Abstract Azobenzene and its derivatives are one of the most widespread molecular scaffolds used in a range of modern applications, as well as in fundamental research. After photoexcitation, azo‐based photoswitches revert back to the most stable isomer on a timescale ( ) that determines the range of potential applications. Attempts to bring to extreme values prompted the development of azobenzene and azoheteroarene derivatives that either rebalance the E ‐ and Z ‐isomer stabilities, or exploit unconventional thermal isomerization mechanisms. In the former case, one successful strategy has been the creation of macrocycle strain, which tends to impact the E / Z stability asymmetrically, and thus significantly modify . On the bright side, bridged derivatives have shown an improved optical switching owing to the higher quantum yields and absence of degradation. However, in most (if not all) cases, bridged derivatives display a reversed thermal stability (more stable Z ‐isomer), and smaller than the acyclic counterparts, which restricts their potential interest to applications requiring a fast forward and backwards switch. In this paper, the impact of alkyl bridges on the thermal stability of phenyl‐azoheteroarenes is investigated by using computational methods, and it is revealed that it is indeed possible to combine such improved photoswitching characteristics while preserving the regular thermal stability (more stable E ‐isomer), and increased values under the appropriate connectivity and bridge length." @default.
- W3089482015 created "2020-10-08" @default.
- W3089482015 creator A5000181491 @default.
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- W3089482015 creator A5013470858 @default.
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- W3089482015 date "2020-11-26" @default.
- W3089482015 modified "2023-10-18" @default.
- W3089482015 title "Tuning the Thermal Stability and Photoisomerization of Azoheteroarenes through Macrocycle Strain**" @default.
- W3089482015 cites W1506967528 @default.
- W3089482015 cites W1967130370 @default.
- W3089482015 cites W1967719392 @default.
- W3089482015 cites W1974157121 @default.
- W3089482015 cites W1987130974 @default.
- W3089482015 cites W1991056234 @default.
- W3089482015 cites W2000798385 @default.
- W3089482015 cites W2002581624 @default.
- W3089482015 cites W2003429013 @default.
- W3089482015 cites W2009483611 @default.
- W3089482015 cites W2010535186 @default.
- W3089482015 cites W2011393168 @default.
- W3089482015 cites W2013723044 @default.
- W3089482015 cites W2016893951 @default.
- W3089482015 cites W2018373119 @default.
- W3089482015 cites W2023173825 @default.
- W3089482015 cites W2025035462 @default.
- W3089482015 cites W2041040278 @default.
- W3089482015 cites W2041041109 @default.
- W3089482015 cites W2045952721 @default.
- W3089482015 cites W2048082410 @default.
- W3089482015 cites W2048134160 @default.
- W3089482015 cites W2054254570 @default.
- W3089482015 cites W2055244237 @default.
- W3089482015 cites W2057116440 @default.
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- W3089482015 cites W2060273633 @default.
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- W3089482015 cites W2066556212 @default.
- W3089482015 cites W2072916332 @default.
- W3089482015 cites W2072965111 @default.
- W3089482015 cites W2083184871 @default.
- W3089482015 cites W2084856161 @default.
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- W3089482015 cites W2113786353 @default.
- W3089482015 cites W2123160053 @default.
- W3089482015 cites W2135049775 @default.
- W3089482015 cites W2151315653 @default.
- W3089482015 cites W2160906879 @default.
- W3089482015 cites W2300768972 @default.
- W3089482015 cites W2317724535 @default.
- W3089482015 cites W2323108463 @default.
- W3089482015 cites W2330760879 @default.
- W3089482015 cites W2342620475 @default.
- W3089482015 cites W2342822021 @default.
- W3089482015 cites W2525478871 @default.
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- W3089482015 cites W2570943593 @default.
- W3089482015 cites W2588118174 @default.
- W3089482015 cites W2589654389 @default.
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- W3089482015 cites W2789057445 @default.
- W3089482015 cites W2792112167 @default.
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- W3089482015 cites W2803076482 @default.
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- W3089482015 doi "https://doi.org/10.1002/chem.202003926" @default.
- W3089482015 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7839710" @default.
- W3089482015 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32991023" @default.
- W3089482015 hasPublicationYear "2020" @default.
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