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• W3089511761 abstract "The model RhO x /CeO 2 systems were prepared by radio‐frequency (RF) plasma sputtering of Rh electrode in O 2 or Ar/O 2 atmosphere. Thermal stability of the systems and their reaction probability towards CO oxidation were studied by X‐ray photoelectron spectroscopy. It was shown that the small oxidized Rh nanoparticles on the CeO 2 surface (RhO x /CeO 2 ) obtained by RF sputtering in O 2 have spectroscopic characteristics close to those of Rh 3+ ions highly dispersed in ceria lattice. The RhO x /CeO 2 system remains stable upon heating in vacuum at 450°C and shows reactivity towards CO oxidation at T > 200°C. RF sputtering in Ar/O 2 atmosphere results in the formation of larger rhodium nanoparticles that are close to Rh 2 O 3 oxide. The Rh 2 O 3 /CeO 2 system demonstrates lower activity in CO oxidation and cannot be reduced at a temperature below 300°C." @default.
• W3089511761 created "2020-10-08" @default.
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• W3089511761 date "2020-09-28" @default.
• W3089511761 modified "2023-09-26" @default.
• W3089511761 title "The activity and thermal stability of RhO_<i>x</i>/CeO₂nanocomposites prepared by radio‐frequency plasma sputtering" @default.
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• W3089511761 doi "https://doi.org/10.1002/sia.6879" @default.
• W3089511761 hasPublicationYear "2020" @default.
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