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• W3089732113 abstract "The Ce–Fe–Mn and Ce–Co–Mn systems have been re-visited with the intent of finding new potential phases for application as permanent magnets. Two new ternary compounds, Ce3(Fe0.638Mn0.362)29 (Nd3(Fe,Ti)29-type, space group P21/c, No. 14, Pearson Symbol mP128) and CeCo8Mn3 (Ce(Ni,Mn)11-type, space group P4/mbm, No. 127, Pearson Symbol tP24) have been discovered in the compositional range where the Ce2(T,Mn)17 (T = Fe, Co) phases are expected to exist with a (H)–Th2Ni17-type structure (space group P63/mmc, No. 194, Pearson Symbol hP38). Detailed investigations of the crystal structures have been performed using X-ray powder diffraction (XRPD) with supporting energy-dispersive X-ray (EDS) analysis. Compositions of the new compounds have been defined based on the EDS analysis as follows: Ce9.7Fe57.5Mn32.8 and Ce9.2Co65.2Mn25.6. A short discussion on the crystal structure peculiarities of the 1:5, 1:11, 1:12, 2:17 and 3:29 compounds in the Ce–T–Mn (T = Fe, Co, Ni, Cu) systems has been made. We present magnetic measurements on selected representatives of the studied phases. The most interesting being the Ce3(Fe0.638Mn0.362)29 phase which has a transition temperature well above room temperature. CeNi4.95Mn6.05 and CeCo8Mn3 exhibits properties characteristic of a canted antiferromagnetic state." @default.
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• W3089732113 date "2021-02-01" @default.
• W3089732113 modified "2023-09-24" @default.
• W3089732113 title "Structural and magnetic properties of new members of the 3:29 phase from the Ce–Fe–Mn system and 1:11 from the Ce–Co–Mn" @default.
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• W3089732113 doi "https://doi.org/10.1016/j.jallcom.2020.157435" @default.
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