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- W3089867835 abstract "Abstract The first example of a BN‐doped cycloparaphenylene BN‐[10]CPP was synthesized and characterized. Its reactivity and photophysical properties were evaluated in direct comparison to its carbonaceous analogues Mes‐[10]CPP and [10]CPP. While the photophysical properties of BN‐[10]CPP remains similar to its carbonaceous analogues, the electronic structure changes associated with the introduction of a 1,2‐azaborine BN heterocycle into a CPP scaffold enables facile and selective late‐stage functionalizations that cannot be accomplished with carbonaceous CPPs. Specifically, Ir‐catalyzed hydrogenation of BN‐[10]CPP selectively reduces the BN heterocyclic ring, which upon hydrolysis produces a rare example of a macrocyclic paraphenylene 6 incorporating the versatile ketone functionality within the macrocyclic ring." @default.
- W3089867835 created "2020-10-08" @default.
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- W3089867835 date "2020-11-16" @default.
- W3089867835 modified "2023-10-12" @default.
- W3089867835 title "A BN‐Doped Cycloparaphenylene Debuts" @default.
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- W3089867835 doi "https://doi.org/10.1002/anie.202010556" @default.
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