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- W3090203417 endingPage "893" @default.
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- W3090203417 abstract "This work reports the synthesis and structure of a large porous zeotype network observed within compound (1) using {Cu2(piv)4} as the linking unit (piv = pivalate). The slow in situ formation of the hmt ligand (hexamethylenetetramine) appears to be key in generating a µ4-bridging mode of the hmt-node. Attempts to improve the low yield of compound (1) using different solvent layer diffusion methods resulted in the µ3-hmt complexes (2) and (3). Both compounds exhibit a 3D network of two intertwined chiral networks. Strong hydrogen bonding present in (3) leads to the formation of intertwined, DNA-like double-helix structures. The use of bulky solvents in the synthesis of compound (4) leads to the structure crystallizing solvent-free. The packing of (4) is dominated by energy minimization, which is achieved when the 1D-“cylinders” pack into the closest possible arrangement. This work highlights the potential for solvent controlled synthesis of extended copper-hmt systems." @default.
- W3090203417 created "2020-10-08" @default.
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- W3090203417 date "2020-10-02" @default.
- W3090203417 modified "2023-09-29" @default.
- W3090203417 title "Varying the Dimensionality of Cu(II)-Based Coordination Polymers Through Solvent Influence" @default.
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- W3090203417 doi "https://doi.org/10.3390/cryst10100893" @default.
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