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- W3090747841 abstract "Crystallization often does not follow the monomer-by-monomer addition pathway described by classical nucleation theory. Instead, the initial steps may involve the formation of larger building blocks, such as crystalline or amorphous nanoparticles, droplets, clusters, complexes, or oligomers, that subsequently undergo assembly into a crystal. These multistep crystallization processes are ubiquitous in mineral formation and biomineralization. In materials synthesis, use of nonclassical crystallization pathways is particularly attractive, because in a multistep crystallization process, the restriction on which crystalline faces can grow is lifted, adding to the versatility of materials architectures that can be obtained. Predicting the outcomes of nonclassical crystallizations by understanding the control parameters that influence crystallization pathways is an important and challenging task. Advancing this understanding is essential for realizing the full potential of nonclassical crystallization in the design of functional materials. In this chapter, the status of the development of a predictive theoretical framework for modeling particle-based crystallization is reviewed." @default.
- W3090747841 created "2020-10-08" @default.
- W3090747841 creator A5077376924 @default.
- W3090747841 date "2020-01-01" @default.
- W3090747841 modified "2023-09-26" @default.
- W3090747841 title "Theoretical Insight into Thermodynamics of Particle-Based Crystallization" @default.
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- W3090747841 doi "https://doi.org/10.1021/bk-2020-1358.ch005" @default.
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