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- W3090826503 abstract "Nanoparticles (NPs) distributed near the interface (in the droplets/matrix) and exactly at the interface are constructed in model polypropylene/polystyrene blends filled with different hydrophobic silica. It is found that the initially refined morphology of blends is stabilized under quiescent annealing by all NPs, especially for NPs exactly at the interface. However, the refined morphology in the shear flow is effectively stabilized by a small number of NPs near the interface, while it becomes exceedingly unstable with high concentrations of interfacial NPs due to the coalescence that resulted from shear-induced destruction of the brittle interface. In extensional flow, extensional thinning of blends is closely related to the NP concentration and the droplet deformation. Moreover, the droplet deformation is significantly promoted by NPs in the matrix but near the interface and low NP concentrations exactly at the interface, but it is obviously suppressed by high NP concentrations due to the brittle interface." @default.
- W3090826503 created "2020-10-08" @default.
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- W3090826503 date "2020-11-01" @default.
- W3090826503 modified "2023-10-14" @default.
- W3090826503 title "Selective distribution of nanoparticles in immiscible blends: Effects on the morphology evolution and rheology in quiescent annealing, shear and extensional flow" @default.
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- W3090826503 doi "https://doi.org/10.1122/8.0000069" @default.
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