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- W3091081657 abstract "An assortment of aromatic ketones was successfully functionalized with a variety of unactivated secondary alcohols that serve as alkylating agents, providing β-disubstituted ketone products in good to excellent yields. Remarkably, challenging substrates such as simple acetophenone derivatives are effectively alkylated under this ruthenium catalysis. The substituted cyclohexanol compounds displayed product-induced diastereoselectivity. Mechanistic studies indicate the involvement of the hydrogen-borrowing pathway in these alkylation reactions. Notably, this selective and catalytic C–C bond-forming reaction requires only a minimal load of catalyst and base and produces H2O as the only byproduct, making this protocol attractive and environmentally benign." @default.
- W3091081657 created "2020-10-08" @default.
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- W3091081657 date "2020-10-01" @default.
- W3091081657 modified "2023-10-14" @default.
- W3091081657 title "Ruthenium-Catalyzed α-Alkylation of Ketones Using Secondary Alcohols to β-Disubstituted Ketones" @default.
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- W3091081657 doi "https://doi.org/10.1021/acs.orglett.0c02787" @default.
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