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• W3091402684 endingPage "812" @default.
• W3091402684 startingPage "806" @default.
• W3091402684 abstract "Abstract Inspired by the exquisite helices in Nature, fabrication of helical materials with controlled handedness has attracted considerable attention. Herein, we report on precis synthesis of single left‐ and right‐handed helical polyisocyanides through living polymerization of achiral monomers using chiral palladium catalysts under helix‐sense‐selective manner. Mechanism study revealed that the yielded helices with opposite handedness showed different activity of the living chain end. The helix with unfavored handedness was self‐terminated, while the one with favored handedness showed high activity and could undergo chain propagation to form a high molecular weight polymer with maintained single‐handed helicity." @default.
• W3091402684 created "2020-10-08" @default.
• W3091402684 creator A5005901473 @default.
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• W3091402684 creator A5045545412 @default.
• W3091402684 creator A5055923434 @default.
• W3091402684 creator A5079780979 @default.
• W3091402684 date "2020-11-12" @default.
• W3091402684 modified "2023-10-16" @default.
• W3091402684 title "Selective Synthesis of Single‐Handed Helical Polymers from Achiral Monomer and a Mechanism Study on Helix‐Sense‐Selective Polymerization" @default.
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