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- W3091705165 abstract "The union of metal‐directed self‐assembly, dynamic covalent chemistry, and sorting gives rise to 3 new unsymmetrical tetrameric disulfide macrocycles. Stepwise sulfur extrusion from the self‐assembled disulfides to, first, thioethers, and then to hydrocarbons by photochemically promoted routes, gives rise to a collection of 7 new thioether and hydrocarbon cyclophanes related to the venerable family of [ n ]paracyclophanes. These methods provide an efficient self‐assembly approach to the synthesis of hydrocarbon macrocycles (related to carbon “nanohoops”), a class of structures that are typically formed in lengthier, stepwise syntheses." @default.
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- W3091705165 date "2020-10-19" @default.
- W3091705165 modified "2023-10-16" @default.
- W3091705165 title "An Efficient Route to Symmetrical and Unsymmetrical Disulfide, Thioether, and Hydrocarbon Cyclophanes" @default.
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- W3091705165 doi "https://doi.org/10.1002/ejoc.202001242" @default.
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