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- W3091867191 abstract "Abstract The design of biomimetic models of metalloenzymes needs to take into account many factors and is therefore a challenging task. We propose in this work an original strategy to control the second coordination sphere of a metal centre and its distal environment. A biomimetic complex, reproducing the first coordination sphere, is encapsulated in a self‐assembled hydrogen‐bonded capsule. The cationic complex is co‐encapsulated with its counter‐anion or with solvent molecules. The capsule is dynamic, allowing a fast in/out exchange of the co‐encapsulated species. It also provides both a hydrogen‐bonding site in the second coordination sphere and a source of proton as it can be deprotonated in the presence of the complex, providing a globally neutral host‐guest assembly. This simple and broad scope strategy is unprecedented in biomimetic studies. The approach appears to be a very promising method for the stabilisation of reactive species and for the study of their reactivity." @default.
- W3091867191 created "2020-10-15" @default.
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- W3091867191 date "2020-11-30" @default.
- W3091867191 modified "2023-09-30" @default.
- W3091867191 title "A Promising Approach for Controlling the Second Coordination Sphere of Biomimetic Metal Complexes: Encapsulation in a Dynamic Hydrogen‐Bonded Capsule" @default.
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- W3091867191 doi "https://doi.org/10.1002/chem.202004370" @default.
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