Matches in SemOpenAlex for { <https://semopenalex.org/work/W3092062228> ?p ?o ?g. }
- W3092062228 endingPage "114691" @default.
- W3092062228 startingPage "114691" @default.
- W3092062228 abstract "The electrode reactions of the Ce3+/Ce couple in molten LiCl–KCl eutectic in the temperature range 723–823 K on solid Mo electrodes were investigated by electrochemical techniques. The mechanism of deposition of metallic cerium has been established. It was found that the cathode reaction is irreversible and proceeds in one stage. The apparent standard Gibbs energy of CeCl3 formation from the elements was calculated. The values of enthalpy and entropy were equal: ΔH* = − 1000.2 kJ/mol, ΔS* = 166.0 J/mol·K. The conditions of high-purity cerium production have been studied. The chemical structure of cathode deposits as well as the surfaces of the crucible were investigated by XRD, ICP and SEM-EDS methods. It was established that the best results for purification of the cathode product from impurities were achieved in the range 40–60 mA/cm2 using a two-stage electrolysis. The amounts of the main impurities in the final product were 0.005 wt% Al, 0.0021 wt% Fe, and 0.003 wt% Si. The total purity of metallic cerium after cleaning was increased up to 99.971 wt% if a vitreous carbon crucible was used." @default.
- W3092062228 created "2020-10-15" @default.
- W3092062228 creator A5007120949 @default.
- W3092062228 creator A5022687420 @default.
- W3092062228 creator A5025183770 @default.
- W3092062228 creator A5028446319 @default.
- W3092062228 creator A5041362889 @default.
- W3092062228 creator A5042241049 @default.
- W3092062228 creator A5055260239 @default.
- W3092062228 creator A5072941063 @default.
- W3092062228 creator A5073557497 @default.
- W3092062228 creator A5085028455 @default.
- W3092062228 date "2020-12-01" @default.
- W3092062228 modified "2023-09-30" @default.
- W3092062228 title "Electrochemical study of reduction Ce(III) ions and production of high purity metallic cerium by electrorefining in fused LiCl-KCl eutectic" @default.
- W3092062228 cites W1967437570 @default.
- W3092062228 cites W2019082037 @default.
- W3092062228 cites W2019961857 @default.
- W3092062228 cites W2026802120 @default.
- W3092062228 cites W2027554777 @default.
- W3092062228 cites W2029362377 @default.
- W3092062228 cites W2043872897 @default.
- W3092062228 cites W2058250795 @default.
- W3092062228 cites W2094080551 @default.
- W3092062228 cites W2106979979 @default.
- W3092062228 cites W2110646689 @default.
- W3092062228 cites W2134438099 @default.
- W3092062228 cites W2597696252 @default.
- W3092062228 cites W2744240760 @default.
- W3092062228 cites W2789621104 @default.
- W3092062228 cites W2884716199 @default.
- W3092062228 cites W2951362412 @default.
- W3092062228 cites W313545802 @default.
- W3092062228 doi "https://doi.org/10.1016/j.jelechem.2020.114691" @default.
- W3092062228 hasPublicationYear "2020" @default.
- W3092062228 type Work @default.
- W3092062228 sameAs 3092062228 @default.
- W3092062228 citedByCount "5" @default.
- W3092062228 countsByYear W30920622282021 @default.
- W3092062228 countsByYear W30920622282022 @default.
- W3092062228 countsByYear W30920622282023 @default.
- W3092062228 crossrefType "journal-article" @default.
- W3092062228 hasAuthorship W3092062228A5007120949 @default.
- W3092062228 hasAuthorship W3092062228A5022687420 @default.
- W3092062228 hasAuthorship W3092062228A5025183770 @default.
- W3092062228 hasAuthorship W3092062228A5028446319 @default.
- W3092062228 hasAuthorship W3092062228A5041362889 @default.
- W3092062228 hasAuthorship W3092062228A5042241049 @default.
- W3092062228 hasAuthorship W3092062228A5055260239 @default.
- W3092062228 hasAuthorship W3092062228A5072941063 @default.
- W3092062228 hasAuthorship W3092062228A5073557497 @default.
- W3092062228 hasAuthorship W3092062228A5085028455 @default.
- W3092062228 hasConcept C113196181 @default.
- W3092062228 hasConcept C120500152 @default.
- W3092062228 hasConcept C121332964 @default.
- W3092062228 hasConcept C146477669 @default.
- W3092062228 hasConcept C147597530 @default.
- W3092062228 hasConcept C147789679 @default.
- W3092062228 hasConcept C163127949 @default.
- W3092062228 hasConcept C17525397 @default.
- W3092062228 hasConcept C178790620 @default.
- W3092062228 hasConcept C179104552 @default.
- W3092062228 hasConcept C18168003 @default.
- W3092062228 hasConcept C185592680 @default.
- W3092062228 hasConcept C2780026712 @default.
- W3092062228 hasConcept C43617362 @default.
- W3092062228 hasConcept C49110097 @default.
- W3092062228 hasConcept C523597863 @default.
- W3092062228 hasConcept C52859227 @default.
- W3092062228 hasConcept C544153396 @default.
- W3092062228 hasConcept C62520636 @default.
- W3092062228 hasConcept C68047255 @default.
- W3092062228 hasConcept C68801617 @default.
- W3092062228 hasConcept C71987851 @default.
- W3092062228 hasConceptScore W3092062228C113196181 @default.
- W3092062228 hasConceptScore W3092062228C120500152 @default.
- W3092062228 hasConceptScore W3092062228C121332964 @default.
- W3092062228 hasConceptScore W3092062228C146477669 @default.
- W3092062228 hasConceptScore W3092062228C147597530 @default.
- W3092062228 hasConceptScore W3092062228C147789679 @default.
- W3092062228 hasConceptScore W3092062228C163127949 @default.
- W3092062228 hasConceptScore W3092062228C17525397 @default.
- W3092062228 hasConceptScore W3092062228C178790620 @default.
- W3092062228 hasConceptScore W3092062228C179104552 @default.
- W3092062228 hasConceptScore W3092062228C18168003 @default.
- W3092062228 hasConceptScore W3092062228C185592680 @default.
- W3092062228 hasConceptScore W3092062228C2780026712 @default.
- W3092062228 hasConceptScore W3092062228C43617362 @default.
- W3092062228 hasConceptScore W3092062228C49110097 @default.
- W3092062228 hasConceptScore W3092062228C523597863 @default.
- W3092062228 hasConceptScore W3092062228C52859227 @default.
- W3092062228 hasConceptScore W3092062228C544153396 @default.
- W3092062228 hasConceptScore W3092062228C62520636 @default.
- W3092062228 hasConceptScore W3092062228C68047255 @default.
- W3092062228 hasConceptScore W3092062228C68801617 @default.
- W3092062228 hasConceptScore W3092062228C71987851 @default.
- W3092062228 hasFunder F4320321001 @default.
- W3092062228 hasFunder F4320323085 @default.