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- W3092083527 abstract "Solid polymer electrolytes (SPEs) have attracted considerable research interest because they are expected to solve the safety problems caused by the liquid electrolytes. However, the low ionic conductivity limits their practical applications. Constructing Li + fast conducting network in SPEs with Li + highly conducting ceramic fillers following the mixed matrix membrane concept have shown their limits in raising the Li + conductivity. Herein, a new strategy using Li + non-conducting fillers like CeO 2 nanowires, is proposed to construct a Li + fast conducting network through SPEs. CeO 2 nanowires can dissociate LiTFSI, which results in a high Li + conductivity through the SPEs near to the fiber surface. This experimental finding is confirmed by analytics (FT-IR, Raman and NMR) and theoretical calculations (DFT-MD and COHP). As a result, the network of interwoven CeO 2 nanowires helps form a continuous Li + fast conducting percolation network through the SPEs. The ionic conductivity of the composite SPEs with 10 wt% CeO 2 nanowires is greatly improved (1.1 × 10 −3 S cm −1 at 60 °C). The Li symmetric cells with this composite electrolyte exhibit good cyclic stability (without short circuiting after 2000 h), and the all-solid-state LiFePO 4 /Li cells present a superior cycling performance (remained 140 mA h g −1 after 100 cycles at 1 C). • Li + non-conducting nanofillers are used to construct Li + fast conducting network. • Dissociation process of LiTFSI on the CeO 2 surface is theoretically simulated. • Novel mechanism for the enhancement of Li + conductivity is proposed." @default.
- W3092083527 created "2020-10-15" @default.
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- W3092083527 date "2021-01-01" @default.
- W3092083527 modified "2023-10-13" @default.
- W3092083527 title "Nanocomposite with fast Li+ conducting percolation network: Solid polymer electrolyte with Li+ non-conducting filler" @default.
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- W3092083527 cites W2036970930 @default.
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- W3092083527 doi "https://doi.org/10.1016/j.nanoen.2020.105475" @default.
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