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• W3092108681 abstract "Oxamic hydrazide (OHA) was utilized as an efficient coreactant of Ru(bpy)32+ for the first time, which can dramatically increase the electrochemiluminescence (ECL) intensity of Ru(bpy)32+ on glassy carbon electrode (GCE). 4-nitrobenzaldehyde (4-NBA), a nitroaromatic compound, has mutagenic and carcinogenic toxicity on humans′ genome and causes a serious impact on the environment. Hence, the detection of its level in biological and environmental samples is of great significance. Interestingly, 4-NBA was found to induce a dramatic quenching for the ECL intensity of the developed Ru(bpy)32+/OHA system owing to the formation of hydrazone product through the nucleophilic addition reaction with OHA. Under optimal conditions, the ECL decreasing value of Ru(bpy)32+/OHA in the presence of 4-NBA is linear in the range of 20 μM to 800 μM with a limit of detection (LOD) of 1.09 μM (signal-to-noise 3 : 1). Finally, this strategy enabled the detection of 4-NBA in tap water with satisfactory recoveries from 97.84 % to 103.56 %." @default.
• W3092108681 created "2020-10-15" @default.
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• W3092108681 date "2020-10-16" @default.
• W3092108681 modified "2023-10-18" @default.
• W3092108681 title "Electrochemiluminescence of Ru(bpy) ₃ ²⁺ /Oxamic Hydrazide and its Application for Selective Detection of 4‐Nitrobenzaldehyde" @default.
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• W3092108681 doi "https://doi.org/10.1002/celc.202001140" @default.
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