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• W3092300985 abstract "We describe the development of the catalytic reductive alkylation of amines with aldehydes under the atmospheric pressure of H2 using a brush-like silicon-nanostructure-supported palladium nanoparticle composite (SiNS-Pd) as a silicon-wafer-based reusable heterogeneous catalyst. The present reaction of primary and secondary amines with various aliphatic and aromatic aldehydes in the presence of the catalyst (0.02-0.05 mol % Pd) gave the corresponding secondary and tertiary amines including Lomerizine and Aticaprant in a 68% quantitative yield without overalkylation. We also designed and fabricated a flow device equipped with SiNS-Pd for microflow reactions, which was applied to the gas-liquid-solid triphasic reaction system (i.e., H2 gas, a substrate solution, and a solid catalyst). A multigram-scale reaction of aniline and benzaldehyde was demonstrated to obtain N-benzylaniline (ca. 4 g/day), in which the internal volume of the flow channel was 43 μL, the residence time was approximately 1 s, and the turnover number (TON) reached 4.0 × 104 in a continuous 24 h run (1.7 × 103 h-1; 0.50 s-1)." @default.
• W3092300985 created "2020-10-15" @default.
• W3092300985 creator A5056534781 @default.
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• W3092300985 date "2020-10-09" @default.
• W3092300985 modified "2023-10-15" @default.
• W3092300985 title "Catalytic Reductive Alkylation of Amines in Batch and Microflow Conditions Using a Silicon-Wafer-Based Palladium Nanocatalyst" @default.
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• W3092300985 doi "https://doi.org/10.1021/acsomega.0c04329" @default.
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• W3092300985 hasPublicationYear "2020" @default.
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