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- W3092433141 abstract "The chemoselective cleavage of a six-membered aromatic ring in biphenylene is reported using an aluminum(I) complex. This type of selectivity is unprecedented. In every example of transition metal mediated C−C σ-bond activation reported to date, the reaction occurs at the central four-membered ring of biphenylene. Insight into the origin of chemoselectivity was obtained through a detailed mechanistic analysis (isolation of an intermediate, DFT studies, activation strain analysis). In conclusion, the divergent reactivity can be attributed to differences in both the symmetry and radial extension of the frontier molecular orbitals of the aluminum(I) fragment compared to that of common transition metal fragments." @default.
- W3092433141 created "2020-10-15" @default.
- W3092433141 creator A5034836508 @default.
- W3092433141 creator A5050325369 @default.
- W3092433141 date "2020-12-01" @default.
- W3092433141 modified "2023-10-02" @default.
- W3092433141 title "Chemoselective C−C σ‐Bond Activation of the Most Stable Ring in Biphenylene**" @default.
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- W3092433141 doi "https://doi.org/10.1002/anie.202011594" @default.
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