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• W3092544134 abstract "In the classical amidation between aromatic ketones and amines, 2.0 equivalents of amines are necessarily required to gain satisfying yields. The specific role of the amine in the direct amidation already puzzled us for a long time. In this work, we disclosed that the amine acts as both reactant and catalyst. Specifically, the determination of reaction intermediates revealed the full mechanism, based on which, the introduction of one equivalent base in the amidation is showcased here that a high yield (∼95 %) can be afforded using only 1.1 equiv. of amine." @default.
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• W3092544134 date "2020-10-01" @default.
• W3092544134 modified "2023-09-25" @default.
• W3092544134 title "Unveiling the reaction process of the amine in direct amidation of aromatic ketones in H ₂ O" @default.
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• W3092544134 doi "https://doi.org/10.1002/open.202000178" @default.
• W3092544134 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7539465" @default.
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