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• W3092675947 abstract "Abstract Tridentate Lewis acids with aligned functions were synthesized based on the rigid framework hexadehydrotribenzo[12]annulene. The backbone and its fluorinated analogue were synthesised in one‐pot syntheses, with alkyne deprotection and Sonogashira cross coupling reaction being carried out in one step. Hydrosilylation of the annulene with chlorohydrosilanes proceeded highly selectively and afforded rigid poly‐Lewis acids with three SiCl 3 or SiCl 2 Me substituents perfectly oriented to one side of the molecule in a single step. The progress of hydrosilylation was investigated by time‐correlated NMR spectroscopic studies. The crystal structures show that the framework is symmetrically functionalised and the silyl substituents are aligned in one direction. To increase the acidity of the Lewis acids the chlorosilyl substituents were fluorinated with SbF 3 . Further investigation of hydrometallation reactions (M=B, Al, Ga, Sn) did not lead to corresponding structures." @default.
• W3092675947 created "2020-10-22" @default.
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• W3092675947 date "2020-12-23" @default.
• W3092675947 modified "2023-10-01" @default.
• W3092675947 title "Chalice‐Type Tridentate Silicon Lewis Acids of <i>C</i>₃ Symmetry in a Single Step Starting from Hexadehydrotribenzo[12]annulene" @default.
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• W3092675947 doi "https://doi.org/10.1002/chem.202004088" @default.
• W3092675947 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7898637" @default.
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