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• W3093150385 abstract "Direct methanol fuel cells (DMFCs) have been shown potential interest in several portable electronics for “green” power generation, however their large-scale commercial production are mostly hampered due to the low activity and high cost of the anode catalysts. In the present study, we report a facile, environmentally friendly, and cost-effective Pd supported on 3D graphene aerogel (Pd/GA) by one step freeze-casting process. The as-synthesized Pd/GA was broadly characterized by XRD, Raman, SEM, and TEM. Morphology observations show that 3D-porous cellular structure of Pd/GA with uniform distribution of 10 nm Pd nanoparticles on the surface of graphene sheets. Based on structural merits, the performance of Pd/GA has been investigated as an anode catalyst for alkaline DMFCs. Pd/GA catalyst shows significantly superior electrocatalytic performance, abnormally high poison tolerance, and stability as compared to the conventional Pd/ carbon black (Vulcan XC-72R) with the same loading (∼20%) of Pd.The superior electrocatalytic performance of Pd/GA towards methanol oxidation can be used in practical application as a promising anode material for DMFCs." @default.
• W3093150385 created "2020-10-22" @default.
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• W3093150385 date "2021-01-01" @default.
• W3093150385 modified "2023-10-16" @default.
• W3093150385 title "Pd supported on 3D graphene aerogel as potential electrocatalyst for alkaline direct methanol fuel cells" @default.
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• W3093150385 doi "https://doi.org/10.1016/j.matpr.2020.08.446" @default.
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