Matches in SemOpenAlex for { <https://semopenalex.org/work/W3093334852> ?p ?o ?g. }
- W3093334852 endingPage "18697" @default.
- W3093334852 startingPage "18687" @default.
- W3093334852 abstract "Incorporating hidden length into polymer chains can improve their mechanical properties, because release of the hidden length under mechanical loads enables localized strain relief without chain fracture. To date, the design of hidden length has focused primarily on the choice of the sacrificial bonds holding the hidden length together. Here we demonstrate the advantages of adding mechanochemical reactivity to hidden length itself, using a new mechanophore that integrates (Z)-2,3-diphenylcyclobutene-1,4-dicarboxylate, with hitherto unknown mechanochemistry, into macrocyclic cinnamate dimers. Stretching a polymer of this mechanophore more than doubles the chain contour length without fracture. DFT calculations indicate that the sequential dissociation of the dimer, followed by cyclobutene isomerization at higher forces yields a chain fracture energy 11 times that of a simple polyester of the same initial contour length and preserves high energy-dissipating capacity up to ∼3 nN. In sonicated solutions cyclobutene isomerizes to two distinct products by competing reaction paths, validating the computed mechanochemical mechanism and suggesting an experimental approach to quantifying the distribution of single-chain forces under diverse loading scenarios." @default.
- W3093334852 created "2020-10-22" @default.
- W3093334852 creator A5007120363 @default.
- W3093334852 creator A5015640756 @default.
- W3093334852 creator A5018734784 @default.
- W3093334852 creator A5037123828 @default.
- W3093334852 creator A5046483460 @default.
- W3093334852 creator A5067228850 @default.
- W3093334852 creator A5078421502 @default.
- W3093334852 creator A5085108258 @default.
- W3093334852 creator A5088510627 @default.
- W3093334852 date "2020-10-16" @default.
- W3093334852 modified "2023-10-18" @default.
- W3093334852 title "A Polymer with Mechanochemically Active Hidden Length" @default.
- W3093334852 cites W1034338475 @default.
- W3093334852 cites W1073836826 @default.
- W3093334852 cites W1251317203 @default.
- W3093334852 cites W1970446046 @default.
- W3093334852 cites W1971215945 @default.
- W3093334852 cites W1976245763 @default.
- W3093334852 cites W1979274326 @default.
- W3093334852 cites W2007104160 @default.
- W3093334852 cites W2017792066 @default.
- W3093334852 cites W2023974158 @default.
- W3093334852 cites W2038016630 @default.
- W3093334852 cites W2042633999 @default.
- W3093334852 cites W2048106449 @default.
- W3093334852 cites W2057173125 @default.
- W3093334852 cites W2058093794 @default.
- W3093334852 cites W2058158146 @default.
- W3093334852 cites W2070057687 @default.
- W3093334852 cites W2086650661 @default.
- W3093334852 cites W2092052237 @default.
- W3093334852 cites W2098026543 @default.
- W3093334852 cites W2117729857 @default.
- W3093334852 cites W2130393758 @default.
- W3093334852 cites W2149922238 @default.
- W3093334852 cites W2155463909 @default.
- W3093334852 cites W2166884124 @default.
- W3093334852 cites W2171488129 @default.
- W3093334852 cites W2320992350 @default.
- W3093334852 cites W2321513796 @default.
- W3093334852 cites W2328878629 @default.
- W3093334852 cites W2470552145 @default.
- W3093334852 cites W2550218292 @default.
- W3093334852 cites W2594752168 @default.
- W3093334852 cites W2602228188 @default.
- W3093334852 cites W2639728117 @default.
- W3093334852 cites W2738342839 @default.
- W3093334852 cites W2743551468 @default.
- W3093334852 cites W2765131536 @default.
- W3093334852 cites W2766083960 @default.
- W3093334852 cites W2892656212 @default.
- W3093334852 cites W2894393675 @default.
- W3093334852 cites W2910821647 @default.
- W3093334852 cites W2953997303 @default.
- W3093334852 cites W2962784850 @default.
- W3093334852 cites W2966740307 @default.
- W3093334852 cites W2999783969 @default.
- W3093334852 cites W3000145417 @default.
- W3093334852 cites W3004551120 @default.
- W3093334852 cites W3007838018 @default.
- W3093334852 cites W3012205571 @default.
- W3093334852 cites W3015052547 @default.
- W3093334852 doi "https://doi.org/10.1021/jacs.0c09220" @default.
- W3093334852 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7596784" @default.
- W3093334852 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33064473" @default.
- W3093334852 hasPublicationYear "2020" @default.
- W3093334852 type Work @default.
- W3093334852 sameAs 3093334852 @default.
- W3093334852 citedByCount "41" @default.
- W3093334852 countsByYear W30933348522021 @default.
- W3093334852 countsByYear W30933348522022 @default.
- W3093334852 countsByYear W30933348522023 @default.
- W3093334852 crossrefType "journal-article" @default.
- W3093334852 hasAuthorship W3093334852A5007120363 @default.
- W3093334852 hasAuthorship W3093334852A5015640756 @default.
- W3093334852 hasAuthorship W3093334852A5018734784 @default.
- W3093334852 hasAuthorship W3093334852A5037123828 @default.
- W3093334852 hasAuthorship W3093334852A5046483460 @default.
- W3093334852 hasAuthorship W3093334852A5067228850 @default.
- W3093334852 hasAuthorship W3093334852A5078421502 @default.
- W3093334852 hasAuthorship W3093334852A5085108258 @default.
- W3093334852 hasAuthorship W3093334852A5088510627 @default.
- W3093334852 hasBestOaLocation W30933348521 @default.
- W3093334852 hasConcept C102931765 @default.
- W3093334852 hasConcept C126661725 @default.
- W3093334852 hasConcept C159467904 @default.
- W3093334852 hasConcept C161790260 @default.
- W3093334852 hasConcept C178790620 @default.
- W3093334852 hasConcept C185592680 @default.
- W3093334852 hasConcept C2776011334 @default.
- W3093334852 hasConcept C2777133900 @default.
- W3093334852 hasConcept C2779546866 @default.
- W3093334852 hasConcept C2780378348 @default.
- W3093334852 hasConcept C508816927 @default.
- W3093334852 hasConcept C521977710 @default.
- W3093334852 hasConceptScore W3093334852C102931765 @default.