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• W3093491396 abstract "A pyrrole ethyl ester with a fused bis(thiadiazolo)benzo unit was prepared by reacting 4-nitrobenzo[1,2-c:3,4-c’]bis(1,2,5)thiadiazole with ethyl isocyanoacetate in the presence of a non-nucleophilic base. Cleavage of the ester moiety, followed by reaction with a chloromethylpyrrole in refluxing pyridine, afforded a tripyrrane and subsequent acid-catalyzed condensation with pyrrole or indene dialdehydes gave porphyrinoids incorporating fused electron-deficient heterocyclic units." @default.
• W3093491396 created "2020-10-29" @default.
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• W3093491396 date "2020-11-01" @default.
• W3093491396 modified "2023-09-27" @default.
• W3093491396 title "Exploring the limitations of the MacDonald ‘3 + 1’ condensation in the preparation of porphyrins with fused electron-withdrawing heterocyclic rings: Synthesis of a bis(thiadiazolo)benzoporphyrin and a related benzocarbaporphyrin" @default.
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• W3093491396 doi "https://doi.org/10.1016/j.tetlet.2020.152576" @default.
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