Matches in SemOpenAlex for { <https://semopenalex.org/work/W3093898569> ?p ?o ?g. }
- W3093898569 endingPage "16420" @default.
- W3093898569 startingPage "16410" @default.
- W3093898569 abstract "Sodium-conducting sulfide glasses are promising materials for the next generation of solid-state batteries. Deep insight into the glass structure is required to ensure a functional design and tailoring of vitreous alloys for energy applications. Using pulsed neutron diffraction supported by first-principles molecular dynamics, we show a structural diversity of Na2S–As2S3 sodium thioarsenate glasses, consisting of long corner-sharing (CS) pyramidal chains CS-(AsSS2/2)k, small AspSq rings (p + q ≤ 11), mixed corner- and edge-sharing oligomers, edge-sharing (ES) dimers ES-As2S4, and isolated (ISO) pyramids ISO-AsS3, entirely or partially connected by sodium species. Polysulfide S–S bridges and structural units with homopolar As–As bonds complete the glass structure, which is basically different from structural motifs predicted by the equilibrium phase diagram. In contrast to superionic silver and sodium sulfide glasses, characterized by a significant population of isolated sulfur species Siso (0.20 < Siso/Stot < 0.28), that is, sulfur connected to only mobile cations M+ with a usual M/Siso stoichiometry of 2, poorly conducting Na2S–As2S3 alloys exhibit a modest Siso fraction of 6.2%." @default.
- W3093898569 created "2020-10-29" @default.
- W3093898569 creator A5032646942 @default.
- W3093898569 creator A5033936609 @default.
- W3093898569 creator A5034961176 @default.
- W3093898569 creator A5040587468 @default.
- W3093898569 creator A5067425313 @default.
- W3093898569 creator A5082384388 @default.
- W3093898569 creator A5083368657 @default.
- W3093898569 date "2020-10-26" @default.
- W3093898569 modified "2023-10-13" @default.
- W3093898569 title "Chemical and Structural Variety in Sodium Thioarsenate Glasses Studied by Neutron Diffraction and Supported by First-Principles Simulations" @default.
- W3093898569 cites W1810694562 @default.
- W3093898569 cites W1862095470 @default.
- W3093898569 cites W1977525014 @default.
- W3093898569 cites W1980226931 @default.
- W3093898569 cites W1981368803 @default.
- W3093898569 cites W198210533 @default.
- W3093898569 cites W1986172482 @default.
- W3093898569 cites W1988091937 @default.
- W3093898569 cites W1989060947 @default.
- W3093898569 cites W1990688594 @default.
- W3093898569 cites W1991095788 @default.
- W3093898569 cites W1991794210 @default.
- W3093898569 cites W1998260426 @default.
- W3093898569 cites W2000770615 @default.
- W3093898569 cites W2002389631 @default.
- W3093898569 cites W2004679145 @default.
- W3093898569 cites W2005955052 @default.
- W3093898569 cites W2007447837 @default.
- W3093898569 cites W2008423326 @default.
- W3093898569 cites W2009568898 @default.
- W3093898569 cites W2015264820 @default.
- W3093898569 cites W2016168218 @default.
- W3093898569 cites W2016717188 @default.
- W3093898569 cites W2021965251 @default.
- W3093898569 cites W2023390323 @default.
- W3093898569 cites W2023649518 @default.
- W3093898569 cites W2041638382 @default.
- W3093898569 cites W2042861541 @default.
- W3093898569 cites W2043025640 @default.
- W3093898569 cites W2045896163 @default.
- W3093898569 cites W2046174089 @default.
- W3093898569 cites W2046275791 @default.
- W3093898569 cites W2048575276 @default.
- W3093898569 cites W2065373916 @default.
- W3093898569 cites W2067336811 @default.
- W3093898569 cites W2073633100 @default.
- W3093898569 cites W2077132713 @default.
- W3093898569 cites W2081477542 @default.
- W3093898569 cites W2109046363 @default.
- W3093898569 cites W2113234830 @default.
- W3093898569 cites W2113617473 @default.
- W3093898569 cites W2126592977 @default.
- W3093898569 cites W2127500147 @default.
- W3093898569 cites W2135282016 @default.
- W3093898569 cites W2277409656 @default.
- W3093898569 cites W2297620602 @default.
- W3093898569 cites W2320462409 @default.
- W3093898569 cites W2321696461 @default.
- W3093898569 cites W2468780812 @default.
- W3093898569 cites W2471358763 @default.
- W3093898569 cites W2522940439 @default.
- W3093898569 cites W2551758058 @default.
- W3093898569 cites W2567278413 @default.
- W3093898569 cites W2770049352 @default.
- W3093898569 cites W2787848371 @default.
- W3093898569 cites W2795907136 @default.
- W3093898569 cites W2944264100 @default.
- W3093898569 cites W2953128973 @default.
- W3093898569 cites W2954543120 @default.
- W3093898569 cites W2989972723 @default.
- W3093898569 cites W2996380557 @default.
- W3093898569 cites W3026551312 @default.
- W3093898569 cites W3124682253 @default.
- W3093898569 doi "https://doi.org/10.1021/acs.inorgchem.0c02220" @default.
- W3093898569 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33104333" @default.
- W3093898569 hasPublicationYear "2020" @default.
- W3093898569 type Work @default.
- W3093898569 sameAs 3093898569 @default.
- W3093898569 citedByCount "11" @default.
- W3093898569 countsByYear W30938985692020 @default.
- W3093898569 countsByYear W30938985692021 @default.
- W3093898569 countsByYear W30938985692022 @default.
- W3093898569 countsByYear W30938985692023 @default.
- W3093898569 crossrefType "journal-article" @default.
- W3093898569 hasAuthorship W3093898569A5032646942 @default.
- W3093898569 hasAuthorship W3093898569A5033936609 @default.
- W3093898569 hasAuthorship W3093898569A5034961176 @default.
- W3093898569 hasAuthorship W3093898569A5040587468 @default.
- W3093898569 hasAuthorship W3093898569A5067425313 @default.
- W3093898569 hasAuthorship W3093898569A5082384388 @default.
- W3093898569 hasAuthorship W3093898569A5083368657 @default.
- W3093898569 hasConcept C115624301 @default.
- W3093898569 hasConcept C144024400 @default.
- W3093898569 hasConcept C144082473 @default.
- W3093898569 hasConcept C147789679 @default.
- W3093898569 hasConcept C149923435 @default.