FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3093949057> ?p ?o ?g. }

• W3093949057 endingPage "120095" @default.
• W3093949057 startingPage "120095" @default.
• W3093949057 abstract "A novel structurally characterized salamo-like ligand H2L contained double terminal pyridine groups was designed and synthesized. The single crystals of the Cu(II) and Ni(II) complexes are grown up through coordination of H2L with Cu(II) and Ni(II) ions, respectively, determined as [Cu(LH)]NO3⋅CH3CH2OH and [{Ni(L)}2]n·n3C5H5N·nCH3COCH3. The Cu(II) atom is located at the N2O2 cavity of the deprotonation ligand (L)2− moiety, but the N atoms of the terminal pyridine groups of the ligand (L)2− moiety is not involved in the coordination, and forms a four-coordinated twisted quadrilateral geometry. While the Ni(II) atom (Ni1 or Ni2) is sited in the N2O2 cavity of the deprotonation ligand (L)2− moiety and forms a plane, the terminal pyridine N atoms from the two adjacent [Ni(L)] moieties also coordinated with the Ni(II) atom in the axial positions to form a slightly distorted octahedral geometry with six-coordination. In the formation of MOFs, the benzene and pyridine rings of the ligand (L)2− moiety are rotated and create an angle, result to form a chiral MOFs using an achiral ligand (L)2− moiety. View of MOFs in the C direction, the Ni(II) complex has four different size of apertures in its structure, and presences a large amount of protonic hydrogen. Spectroscopic analyses of H2L and its Cu(II) and Ni(II) complexes are performed using IR, UV–Vis and fluorescence spectroscopy. Compared with the Cu(II) complex, the Ni(II) complex has better thermal stability. The magnetic analyses were also carried out. Hirshfeld surfaces analyses are carried out to analyze various short-range interactions in H2L and its Cu(II) complex." @default.
• W3093949057 created "2020-10-29" @default.
• W3093949057 creator A5018270979 @default.
• W3093949057 creator A5027945396 @default.
• W3093949057 creator A5028468937 @default.
• W3093949057 creator A5059511373 @default.
• W3093949057 creator A5085558225 @default.
• W3093949057 date "2021-02-01" @default.
• W3093949057 modified "2023-10-02" @default.
• W3093949057 title "Investigation on structurally different Cu(II) and Ni(II) complexes constructed from a novel pyridine-terminal salamo-like ligand" @default.
• W3093949057 cites W1975235255 @default.
• W3093949057 cites W1993036969 @default.
• W3093949057 cites W2013889062 @default.
• W3093949057 cites W2016029216 @default.
• W3093949057 cites W2022730250 @default.
• W3093949057 cites W2026985591 @default.
• W3093949057 cites W2029129196 @default.
• W3093949057 cites W2051812710 @default.
• W3093949057 cites W2085314361 @default.
• W3093949057 cites W2097579200 @default.
• W3093949057 cites W2102750563 @default.
• W3093949057 cites W2312866138 @default.
• W3093949057 cites W2314999739 @default.
• W3093949057 cites W2332253101 @default.
• W3093949057 cites W2537376645 @default.
• W3093949057 cites W2551501548 @default.
• W3093949057 cites W2569556614 @default.
• W3093949057 cites W2600294480 @default.
• W3093949057 cites W2615193832 @default.
• W3093949057 cites W2623947064 @default.
• W3093949057 cites W2737929936 @default.
• W3093949057 cites W2760345354 @default.
• W3093949057 cites W2782602425 @default.
• W3093949057 cites W2793067282 @default.
• W3093949057 cites W2907088175 @default.
• W3093949057 cites W2913336977 @default.
• W3093949057 cites W2914807962 @default.
• W3093949057 cites W2917428907 @default.
• W3093949057 cites W2922305891 @default.
• W3093949057 cites W2937415485 @default.
• W3093949057 cites W2946335983 @default.
• W3093949057 cites W2948267881 @default.
• W3093949057 cites W2950973504 @default.
• W3093949057 cites W2953913272 @default.
• W3093949057 cites W2954190634 @default.
• W3093949057 cites W2955748095 @default.
• W3093949057 cites W2971378173 @default.
• W3093949057 cites W2972126398 @default.
• W3093949057 cites W2983792637 @default.
• W3093949057 cites W2984104485 @default.
• W3093949057 cites W2988346342 @default.
• W3093949057 cites W2989816610 @default.
• W3093949057 cites W2996203056 @default.
• W3093949057 cites W2996350367 @default.
• W3093949057 cites W2999412659 @default.
• W3093949057 cites W3006647934 @default.
• W3093949057 cites W3007657416 @default.
• W3093949057 cites W3009573438 @default.
• W3093949057 cites W3012817463 @default.
• W3093949057 cites W3014814327 @default.
• W3093949057 cites W3020878054 @default.
• W3093949057 cites W3023117305 @default.
• W3093949057 cites W3023603602 @default.
• W3093949057 cites W3024468314 @default.
• W3093949057 cites W3025111044 @default.
• W3093949057 cites W3033511205 @default.
• W3093949057 cites W3035144715 @default.
• W3093949057 cites W3036511872 @default.
• W3093949057 cites W3038253581 @default.
• W3093949057 cites W3048053348 @default.
• W3093949057 cites W3048149748 @default.
• W3093949057 cites W3083211974 @default.
• W3093949057 cites W4235143188 @default.
• W3093949057 doi "https://doi.org/10.1016/j.ica.2020.120095" @default.
• W3093949057 hasPublicationYear "2021" @default.
• W3093949057 type Work @default.
• W3093949057 sameAs 3093949057 @default.
• W3093949057 citedByCount "62" @default.
• W3093949057 countsByYear W30939490572021 @default.
• W3093949057 countsByYear W30939490572022 @default.
• W3093949057 countsByYear W30939490572023 @default.
• W3093949057 crossrefType "journal-article" @default.
• W3093949057 hasAuthorship W3093949057A5018270979 @default.
• W3093949057 hasAuthorship W3093949057A5027945396 @default.
• W3093949057 hasAuthorship W3093949057A5028468937 @default.
• W3093949057 hasAuthorship W3093949057A5059511373 @default.
• W3093949057 hasAuthorship W3093949057A5085558225 @default.
• W3093949057 hasConcept C112887158 @default.
• W3093949057 hasConcept C115624301 @default.
• W3093949057 hasConcept C116569031 @default.
• W3093949057 hasConcept C118629725 @default.
• W3093949057 hasConcept C145148216 @default.
• W3093949057 hasConcept C155647269 @default.
• W3093949057 hasConcept C170493617 @default.
• W3093949057 hasConcept C178790620 @default.
• W3093949057 hasConcept C185592680 @default.
• W3093949057 hasConcept C194196696 @default.
• W3093949057 hasConcept C198819137 @default.

• next