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- W3094080659 abstract "Naturally occurring sugar-based monomers are attractive substrates in the design of functional glycopolymers. In this study, we report on the development of D-galactose based organogels of varying crosslink density capable of selective adsorption of dyes and solvents. Free radical polymerization of 6-O-methacryloyl-1,2;3,4-di-O-isopropylidene-D-galactose in the presence of nonamethylene glycoldimethacrylate generated novel crosslinked polymers OG10, OG15 and OG20 with 10, 15 and 20 wt% crosslinker, respectively. Depending on the nature of the solvent, OG10 undergoes swelling upto 935%. The negative zeta potential, as determined from DLS measurements, and the gelation ability suggested the potential utility of the polymer for dye removal from water. OG10 displayed significant adsorption of rhodamine B (RhB) (>95%), crystal violet (>93%), and methylene blue (>70%) dyes as well as the selective adsorption of >90% RhB from a solution containing both RhB and methyl orange. These porous organogels are also found to be suitable for phase-selective removal of organic solvents." @default.
- W3094080659 created "2020-10-29" @default.
- W3094080659 creator A5015268217 @default.
- W3094080659 creator A5068328356 @default.
- W3094080659 date "2020-12-01" @default.
- W3094080659 modified "2023-10-10" @default.
- W3094080659 title "D-galactose-based organogelator for phase-selective solvent removal and sequestration of cationic dyes" @default.
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- W3094080659 doi "https://doi.org/10.1016/j.reactfunctpolym.2020.104766" @default.
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