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- W3094143018 abstract "Oxide is an attractive linker for building polymetallic complexes that provide molecular models for metal oxide activity, but studies of these systems are limited to metals in high oxidation states. Herein, we synthesized and characterized the molecular and electronic structure of diuranium bridged UIII/UIV and UIII/UIII complexes. Reactivity studies of these complexes revealed that the U−O bond is easily broken upon addition of N-heterocycles resulting in the delivery of a formal equivalent of UIII and UII, respectively, along with the uranium(IV) terminal-oxo coproduct. In particular, the UIII/UIII oxide complex effects the reductive coupling of pyridine and two-electron reduction of 4,4′-bipyridine affording unique examples of diuranium(III) complexes bridged by N-heterocyclic redox-active ligands. These results provide insight into the chemistry of low oxidation state metal oxides and demonstrate the use of oxo-bridged UIII/UIII complexes as a strategy to explore UII reactivity." @default.
- W3094143018 created "2020-10-29" @default.
- W3094143018 creator A5000346105 @default.
- W3094143018 creator A5016619652 @default.
- W3094143018 creator A5034832665 @default.
- W3094143018 creator A5051819146 @default.
- W3094143018 creator A5086573323 @default.
- W3094143018 creator A5086637541 @default.
- W3094143018 date "2020-12-14" @default.
- W3094143018 modified "2023-10-16" @default.
- W3094143018 title "Delivery of a Masked Uranium(II) by an Oxide‐Bridged Diuranium(III) Complex" @default.
- W3094143018 cites W1532536342 @default.
- W3094143018 cites W1854208727 @default.
- W3094143018 cites W1964172910 @default.
- W3094143018 cites W1971038878 @default.
- W3094143018 cites W1971118069 @default.
- W3094143018 cites W1974407288 @default.
- W3094143018 cites W1976436568 @default.
- W3094143018 cites W1981180548 @default.
- W3094143018 cites W1984412742 @default.
- W3094143018 cites W1986740957 @default.
- W3094143018 cites W1987343831 @default.
- W3094143018 cites W1991753813 @default.
- W3094143018 cites W1993363646 @default.
- W3094143018 cites W1996713841 @default.
- W3094143018 cites W1999670950 @default.
- W3094143018 cites W2002509876 @default.
- W3094143018 cites W2003650145 @default.
- W3094143018 cites W2004454178 @default.
- W3094143018 cites W2004689978 @default.
- W3094143018 cites W2008759218 @default.
- W3094143018 cites W2010324953 @default.
- W3094143018 cites W2015141385 @default.
- W3094143018 cites W2025913651 @default.
- W3094143018 cites W2026041572 @default.
- W3094143018 cites W2027060669 @default.
- W3094143018 cites W2027891743 @default.
- W3094143018 cites W2035100460 @default.
- W3094143018 cites W2038540899 @default.
- W3094143018 cites W2041325755 @default.
- W3094143018 cites W2048978415 @default.
- W3094143018 cites W2055038447 @default.
- W3094143018 cites W2060201123 @default.
- W3094143018 cites W2073216107 @default.
- W3094143018 cites W2081353571 @default.
- W3094143018 cites W2088454672 @default.
- W3094143018 cites W2091444833 @default.
- W3094143018 cites W2095506457 @default.
- W3094143018 cites W2102230437 @default.
- W3094143018 cites W2102513724 @default.
- W3094143018 cites W2103504679 @default.
- W3094143018 cites W2107473053 @default.
- W3094143018 cites W2116920507 @default.
- W3094143018 cites W2117118985 @default.
- W3094143018 cites W2122267363 @default.
- W3094143018 cites W2123948271 @default.
- W3094143018 cites W2141127077 @default.
- W3094143018 cites W2148181964 @default.
- W3094143018 cites W2157029048 @default.
- W3094143018 cites W2160813734 @default.
- W3094143018 cites W2185386008 @default.
- W3094143018 cites W2258779832 @default.
- W3094143018 cites W2281936655 @default.
- W3094143018 cites W2290662340 @default.
- W3094143018 cites W2315962296 @default.
- W3094143018 cites W2318035632 @default.
- W3094143018 cites W2320776894 @default.
- W3094143018 cites W2321412785 @default.
- W3094143018 cites W2322644217 @default.
- W3094143018 cites W2329403064 @default.
- W3094143018 cites W2329978764 @default.
- W3094143018 cites W2332019390 @default.
- W3094143018 cites W2334083603 @default.
- W3094143018 cites W2417258644 @default.
- W3094143018 cites W2475091130 @default.
- W3094143018 cites W2560937116 @default.
- W3094143018 cites W2573996428 @default.
- W3094143018 cites W2585862636 @default.
- W3094143018 cites W2588831820 @default.
- W3094143018 cites W2592667086 @default.
- W3094143018 cites W270132463 @default.
- W3094143018 cites W2739085298 @default.
- W3094143018 cites W2770994630 @default.
- W3094143018 cites W2887714251 @default.
- W3094143018 cites W2892178064 @default.
- W3094143018 cites W2898867237 @default.
- W3094143018 cites W2902612392 @default.
- W3094143018 cites W2907617758 @default.
- W3094143018 cites W2950393674 @default.
- W3094143018 cites W2951244216 @default.
- W3094143018 cites W2952139302 @default.
- W3094143018 cites W2979585551 @default.
- W3094143018 cites W2989176219 @default.
- W3094143018 cites W2994920601 @default.
- W3094143018 cites W3007767568 @default.
- W3094143018 cites W3022216159 @default.
- W3094143018 cites W3035681311 @default.
- W3094143018 cites W370619834 @default.