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- W3094391656 endingPage "18752" @default.
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- W3094391656 abstract "[Cp*RuCl]4 catalyzes the addition of iPr3SiC≡CX (X = H, Cl) across internal alkynes with formation of 1,3-enyne or 1-chloro-1,3-enyne derivatives, respectively; the reaction follows an unorthodox trans-addition mode. The well-balanced affinities of the different reaction partners to the ruthenium catalyst ensure that crossed addition prevails over homodimerization of the individual components, as can be deduced from spectroscopic and crystallographic data of various intermediates; this includes a dinuclear complex in which an internal alkyne bridges two [Cp*RuCl] fragments." @default.
- W3094391656 created "2020-10-29" @default.
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- W3094391656 date "2020-10-23" @default.
- W3094391656 modified "2023-10-16" @default.
- W3094391656 title "Ruthenium-Catalyzed <i>trans</i>-Hydroalkynylation and <i>trans</i>-Chloroalkynylation of Internal Alkynes" @default.
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- W3094391656 doi "https://doi.org/10.1021/jacs.0c08582" @default.
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