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- W3094562930 abstract "• Investigation of stability of commonly used diazides by DSC. • 1,3-Diazido-propanone shows an explosive event starting at 100 °C (−1047 J g −1 ). • Similar low Smith́s ratios of diazides do not assure comparable thermal behavior. An investigation into the stability of three commonly used diazides (1,3-diazido-propane, 1,3-diazido-propan-2-ol, and 1,3-diazido-propanone) was performed. Despite their use in synthesis, no previous investigation of their thermal stability has been reported. DSC analysis revealed a strong difference in thermal behavior, despite very similar nitrogen content in their structures. While 1,3-diazido-propane and 1,3-diazido-propan-2-ol showed thermal stability up to 175 °C, the carbonyl parent showed an exothermic event starting at 100 °C and culminating at 138 °C (−1047 J g −1 ), representing a significant risk. This potentially explosive behavior seems to reflect the lack of stability at normal temperatures (in our case 40 °C), where no chemical reaction was observed in its attempted transformation into bistriazoles, compared to the other diazides which gave good yields." @default.
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- W3094562930 date "2020-11-01" @default.
- W3094562930 modified "2023-09-24" @default.
- W3094562930 title "Are diazides really dangerous compounds under ordinary conditions?" @default.
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- W3094562930 doi "https://doi.org/10.1016/j.tetlet.2020.152574" @default.
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