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- W3094570129 endingPage "4449" @default.
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- W3094570129 abstract "The complexes of group 13 element trispentafluorophenyl derivatives E(C6F5)3 (E = B, Al, Ga, In) with diethyl ether of 1:1 composition have been synthesized and structurally characterized. All compounds are isostructural. Thermal stability studies reveal that at elevated temperatures all complexes decompose with pentafluorobenzene evolution. The geometries and thermodynamic characteristics for the dissociation reactions of the compounds have been computed using three DFT methods. The 1H NMR α-proton chemical shifts for the coordinated ether in deuteriobenzene and in CD2Cl2 solutions correlate with gas phase dissociation enthalpies of the complexes. Potentially high Lewis acidity of B(C6F5)3 is hindered by the large pyramidalization energy of the acceptor moiety." @default.
- W3094570129 created "2020-10-29" @default.
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- W3094570129 date "2020-11-12" @default.
- W3094570129 modified "2023-09-26" @default.
- W3094570129 title "Structural and Energetic Features of Group 13 Element Trispentafluorophenyl Complexes with Diethyl Ether" @default.
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- W3094570129 doi "https://doi.org/10.1002/ejic.202000815" @default.
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