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• W3094851139 endingPage "5264" @default.
• W3094851139 startingPage "5256" @default.
• W3094851139 abstract "Grain size effect plays a vital role in piezoelectric performance from both scientific and technological view. However, the underlying structural mechanism related to grain size is still unclear. In the present study, the structural mechanism of grain size effect on piezoelectric performance has been revealed in the prototype Pb(Zr,Ti)O3 system by using in-situ synchrotron X-ray diffraction. The miniaturization of grain size tends to favor the appearance of higher symmetric tetragonal phase, while a single monoclinic phase is determined in the coarse-grained ceramics. The direct structural evidence reveals that both tetragonal and monoclinic phases in the fine-grained ceramics are less sensitive to the electric field, corresponding to the inferior piezoelectric performance, while the single monoclinic phase in the coarse-grained ceramics is more active to be driven by the electric field, generating good piezoelectric behavior. Both domain switching ability and lattice strain are suppressed with decreasing grain size, which directly leads to the deterioration in piezoelectric performance. The current results will benefit the structural understanding of the size effect of piezoelectric and other related systems." @default.
• W3094851139 created "2020-11-09" @default.
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• W3094851139 date "2021-02-01" @default.
• W3094851139 modified "2023-09-23" @default.
• W3094851139 title "Structural origin of size effect on piezoelectric performance of Pb(Zr,Ti)O3" @default.
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• W3094851139 doi "https://doi.org/10.1016/j.ceramint.2020.10.106" @default.
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