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- W3095184412 abstract "To show that artifacts can readily form during research on marine natural products, a common marine sesquiterpenoid 1 was treated with sunlight in the presence of a pigment. Another set of solutions were prepared and kept in shade under the bench for two weeks as negative controls. As a result, four oxygenated derivatives 2–5 were obtained. A unique structure of a highly oxidized molecule 5 was solved by X-ray crystallography. A marine cadinane-class sesquiterpenoid 1 was treated with sunlight in the presence of rose bengal. After forming hydroperoxide 2 with 1O2 oxidation, further oxidized derivatives 3–5 were obtained and their structures were characterized with possible pathways. A unique structure of 5, having a little similarity to the antimalarial agent artemisinin, was solved by X-ray crystallography." @default.
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- W3095184412 date "2021-02-05" @default.
- W3095184412 modified "2023-10-16" @default.
- W3095184412 title "Photooxidation Products from a Marine Cadinane Sesquiterpenoid" @default.
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- W3095184412 doi "https://doi.org/10.1246/cl.200672" @default.
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