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- W3095462927 abstract "Asymmetric hydrogenation of 2-aryl-3-phthalimidopyridinium salts catalyzed by the Ir/SegPhos catalytic system was described, leading to the corresponding chiral piperidine derivatives bearing two contiguous chiral centers, with high levels of enantioselectivities and diastereoselectivities. A gram-scale experiment has demonstrated the utility of this approach. The phthaloyl group could be easily removed and then smoothly converted to key intermediate (+)-CP-99994 as one of the neurokinin 1 receptor antagonists." @default.
- W3095462927 created "2020-11-09" @default.
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- W3095462927 date "2020-11-04" @default.
- W3095462927 modified "2023-10-18" @default.
- W3095462927 title "Asymmetric Hydrogenation of 2-Aryl-3-phthalimidopyridinium Salts: Synthesis of Piperidine Derivatives with Two Contiguous Stereocenters" @default.
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- W3095462927 doi "https://doi.org/10.1021/acs.orglett.0c03261" @default.
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