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- W3095955648 abstract "Homoconjugation and intramolecular through-space charge transfers are molecular phenomena that have been studied since the 1960s. A detailed understanding and control of these effects would provide a tool to tune the optoelectronic properties of organic molecules in respect of the necessities for applications such as for organic electronics. Triptycene is a perfect candidate to investigate homoconjugation effects due to its three-dimensional alignment of three aromatic phenylene units, separated by two methine bridges. Here, a series of 16 π-extended triptycenes with up to three different permuted electron-accepting units and an electron-rich veratrole unit are studied in detail by UV/vis spectroscopy and cyclovoltammetry in combination with DFT calculations to get a deeper understanding of homoconjugation and charge-transfer processes of triptycenes. Furthermore, the gained knowledge can be exploited to construct triptycene-based electron acceptors with fine-tuned adjustment of electronic properties, such as electron affinities, by thorough choice of the aromatic blades that interact through homoconjugation." @default.
- W3095955648 created "2020-11-09" @default.
- W3095955648 creator A5007501482 @default.
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- W3095955648 date "2020-11-04" @default.
- W3095955648 modified "2023-10-18" @default.
- W3095955648 title "Homoconjugation and Intramolecular Charge Transfer in Extended Aromatic Triptycenes with Different π-Planes" @default.
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- W3095955648 doi "https://doi.org/10.1021/acs.joc.0c02100" @default.
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