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- W3096160990 abstract "Catalytic asymmetric conjugate allylation of unsaturated carbonyl compounds is usually difficult to achieve, as 1,2-addition proceeds dominantly and high asymmetric induction is a challenging task. Herein, we disclose a copper(I)-NHC complex catalyzed asymmetric 1,6-conjugate allylation of 2,2-dimethyl-6-alkenyl-4H-1,3-dioxin-4-ones. The phenolic hydroxyl group in NHC ligands is found to be pivotal to obtain the desired products. Both aryl group and alkyl group at δ-position are well tolerated with the corresponding products generated in moderate to high yields and high enantioselectivity. Moreover, both 2-substituted and 3-substituted allylboronates serve as acceptable allylation reagents. At last, the synthetic utility of the products is demonstrated in several transformations by means of the versatile terminal olefin and dioxinone groups." @default.
- W3096160990 created "2020-11-09" @default.
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- W3096160990 date "2020-10-30" @default.
- W3096160990 modified "2023-09-26" @default.
- W3096160990 title "Copper(I)-catalyzed asymmetric 1,6-conjugate allylation" @default.
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- W3096160990 doi "https://doi.org/10.1038/s41467-020-19293-9" @default.
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