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- W3096291292 abstract "Abstract The equilibrium solubility of meloxicam (3) in {Carbitol® (1) + water (2)} mixtures at several temperatures from 293.15 K to 313.15 K has been determined and correlated by means of some well-known thermodynamic correlation models. Solubility increases 1144 times, from x3 = 1.137 × 10−6 in neat water to x3 = 1.300 × 10−3 in neat Carbitol® at 298.15 K. By using the van't Hoff and Gibbs equations the respective apparent thermodynamic quantities of the dissolution and mixing processes, namely Gibbs energy, enthalpy, and entropy, were calculated. Apparent dissolution enthalpies vary from a minimum of 7.7 kJ mol−1 in neat water to a maximum of 32.3 kJ mol−1 in the mixture x1 = 0.10. Moreover, apparent dissolution entropies vary from a minimum of −88.0 J mol−1 K−1 in neat water to a maximum of 9.9 J mol−1 K−1 in the mixture x1 = 0.10. Non-linear enthalpy–entropy relationship was observed for meloxicam in the plot of enthalpy vs. Gibbs energy exhibiting negative slope in the composition region 0.00" @default.
- W3096291292 created "2020-11-09" @default.
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- W3096291292 date "2021-02-01" @default.
- W3096291292 modified "2023-09-24" @default.
- W3096291292 title "Solubility of meloxicam in (Carbitol® + water) mixtures: Determination, correlation, dissolution thermodynamics and preferential solvation" @default.
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- W3096291292 doi "https://doi.org/10.1016/j.molliq.2020.114671" @default.
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