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• W3096829920 abstract "The equilibrium geometries for the ground state of the adducts formed between alkyl iodides (RI) and chlorine (Cl) atoms were optimized, and the enthalpies of adduct formations (EAFs) were obtained. The EAFs decreased when the number of alkyl substituents on the C atom bonded to I atom was increased. This trend suggests that the amount of charge transferred from the electron-donating alkyl group to ICl increases in accordance with the number of substituents, which results in the stabilization of the adduct. Charge density distribution between the Cl and H atoms was an additional mechanism to stabilize the adducts." @default.
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• W3096829920 date "2021-01-01" @default.
• W3096829920 modified "2023-10-02" @default.
• W3096829920 title "Theoretical study on the enthalpies of adduct formation between alkyl iodides and chlorine atoms" @default.
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• W3096829920 doi "https://doi.org/10.1016/j.cplett.2020.138140" @default.
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